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A Trimer of Ultrafast Nanomotors: Synthesis, Photochemistry and Self-Assembly on Graphite

机译:超快纳米电机的三聚体:石墨上的合成,光化学和自组装

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摘要

Synthetic molecular motors may play an essential role in the development of nanoscale mechanical devices, as evident from the many fascinating natural systems that use nanometre-sized motors to drive crucial biological processes.[ 1, 2] Biological motors such as the bacterial flagellar motor pose a major challenge to emulate and provide a source of inspiration that has spurred the construction of a wide range of molecular systems in which motion is controlled by chemical, electrochemical, photochemical or thermal input.[3C8] The structural modifications induced in such complex molecular systems can be observed by scanning tunnelling microscopy (STM) in chemisorbed and physisorbed monolayers,[ 9, 10] in particular under ambient conditions.[11, 12]
机译:合成分子马达可能在纳米级机械设备的开发中起着至关重要的作用,这从许多使用纳米级马达驱动重要的生物过程的引人入胜的自然系统中就可以看出。[1,2]生物马达,例如细菌鞭毛马达的姿势模仿和提供灵感的主要挑战促使了分子系统的广泛构建,其中通过化学,电化学,光化学或热输入来控制运动。[3C8]在这种复杂分子系统中引起的结构修饰可以通过扫描隧道显微镜(STM)在化学吸附和物理吸附的单层中观察到[9,10],特别是在环境条件下。[11,12]

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