Oxygen-Atom Transfer by a Naked Manganese(V)–Oxo–Porphyrin Complex Reveals Axial Ligand Effect

Maria Elisa Crestoni; Simonetta Fornarini; Francesco Lanucara

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Oxygen-Atom Transfer by a Naked Manganese(V)–Oxo–Porphyrin Complex Reveals Axial Ligand Effect

机译：裸锰（V）-氧-卟啉配合物的氧原子转移揭示了轴向配体效应

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High-valent transition-metal–oxo complexes are electrophilic oxidants implicated in a variety of biological processes and chemical transformations.~[1] Manganese(V)–oxo species are suggested to be crucial intermediates in the epoxidation of a wide range of alkenes and they provide useful functional models for the active species of heme-containing monooxygenases, including cytochrome P450 enzymes. Manganese–oxo units are also found at the core of photoACHTUNGTRENUNGsystem II, performing oxidation of water to oxygen.~[2]

机译：高价过渡金属-氧配合物是亲电子氧化剂，涉及多种生物过程和化学转化。[1]锰（V）-氧代物种被认为是多种烯烃和环氧化物环氧化的关键中间体。它们为含血红素的单加氧酶（包括细胞色素P450酶）的活性种提供了有用的功能模型。在photoACHTUNGTRENUNGsystem II的核心中还发现了锰-氧单元，将水氧化成氧气。[2]

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《Chemistry: A European journal》 |2009年第32期|共4页
作者
Maria Elisa Crestoni; Simonetta Fornarini; Francesco Lanucara;
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正文语种 eng
中图分类应用化学;
关键词
epoxidation; kinetics; mass spectrometry; manganese; oxido ligands; porphyrinoids;

机译：环氧化;动力学;质谱;锰;氧化配体;卟啉;

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1. Oxygen-Atom Transfer by a Naked Manganese(V)–Oxo–Porphyrin Complex Reveals Axial Ligand Effect [J] . Maria Elisa Crestoni, Simonetta Fornarini, Francesco Lanucara Chemistry: A European journal . 2009,第32期

机译：裸锰（V）-氧-卟啉配合物的氧原子转移揭示了轴向配体效应
2. Effect of Imidazole and Phenolate Axial Ligands on the Electronic Structure and Reactivity of Oxoiron(IV) Porphyrin π-Cation Radical Complexes: Drastic Increase in Oxo-Transfer and Hydrogen Abstraction Reactivities [J] . Akihiro Takahashi, Takuya Kurahashi, Hiroshi Fujii Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2009,第6期

机译：咪唑和苯酚酸酯轴向配体对氧化铁（IV）卟啉π-阳离子自由基配合物的电子结构和反应性的影响：氧转移和氢提取反应性的急剧增加
3. Oxygen-Atom Transfer Reactivity of Axially Ligated Mn(Ⅴ)-Oxo Complexes: Evidence for Enhanced Electrophilic and Nucleophilic Pathways [J] . Heather M. Neu, Tzuhsiung Yang, Regina A. Baglia, Journal of the American Chemical Society . 2014,第39期

机译：轴向连接的Mn（Ⅴ）-氧代配合物的氧原子转移反应性：亲电和亲核途径增强的证据。
4. Charge transfer at the interface between aqueous and organic solution containing an oxidized porphyrin manganese complex [C] . (missing) International Beijing conference and exhibition on instrumental analysis . 2003

机译：含有氧化卟啉锰复合物的水性和有机溶液之间的界面的电荷转移
5. MANGANESE(II) AND COBALT(III) COMPLEXES OF MULTIDENTATE LIGANDS: I. MANGANESE(II) COMPLEXES OF A MACROCYCLIC PENTADENTATE LIGAND. II. COBALT(III) COMPLEXES OF LINEAR TETRAMINE LIGANDS. [D] . HAMILTON, HOBART GORDON, JR. 1968

机译：多齿配体的锰（II）和钴（III）配合物：I.大环戊二烯配体的锰（II）配合物。二。线性叔丁胺配体的钴（III）配合物。
6. DramaticallyAccelerated Selective Oxygen-Atom Transferby a Nonheme Iron(IV)-Oxo Complex: Tuning of the First and SecondCoordination Spheres [O] . LelandR. Widger, Casey G. Davies, Tzuhsiung Yang, -1

机译：戏剧性地加速选择性氧原子转移非血红素铁（IV）-氧配合物的合成：第一和第二调协调领域
7. Oxygen-Atom Transfer Reactivity of Axially Ligated Mn (V)–Oxo Complexes: Evidence for Enhanced Electrophilic and Nucleophilic Pathways [O] . Neu, Heather M., Yang, Tzuhsiung, Baglia, Regina A., 2014

机译：轴向连接的mn（V）-Oxo配合物的氧原子转移反应性：增强亲电和亲核通路的证据
8. Ligand-Centered Electron-Transfer Redox Processes for Manganese, Iron, and Cobalt Complexes in Relation to Selected Catalytic Systems. [R] . Richert, S. A. 1989

机译：与选定的催化体系相关的锰，铁和钴配合物的配体中心电子转移氧化还原过程。

Oxygen-Atom Transfer by a Naked Manganese(V)–Oxo–Porphyrin Complex Reveals Axial Ligand Effect

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