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One Solvent Induces a Series of Structural Transitions in MonodendronMolecular Self-Assembly from Lamellar to Quadrangular to Hexagonal

机译:一种溶剂在单树枝状分子中引起一系列结构转变,从层状分子到四边形再到六角形

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摘要

Self-assembly and self-organization are crucial and neces-sary processes in all living organisms and are of ever in-creasing importance in chemistry and materials sciences.~[1]These processes play a critical role in the so-called "bottom-up" strategy of nanofabrication and are considered to be apromising supplement to microfabrication.~[2]Self-assembledmolecular patterns with control of structure and derivedconcomitant function could provide essential materials andelements for the construction of nanodevices.~[3]In a func-tional molecular nanostructure, molecules act as a functionalcomponent that could be employed to fabricate differentsurface patterns with expected symmetry and structure. Amain challenge in nanodevice fabrication on a two-dimen-sional (2D) surface by using functional molecules is to real-ize molecular patterns from molecular passive and spontane-ous adsorption to selected organization.
机译:自组装和自组织是所有生命有机体中必不可少的关键过程,在化学和材料科学中越来越重要。〜[1]这些过程在所谓的“底部结构”中起着至关重要的作用。 〜[2]具有结构和衍生伴随功能的控制的自组装分子图案可以为纳米器件的构造提供必要的材料和元素。〜[3]在功能上在分子纳米结构中,分子充当功能成分,可以用来制造具有预期对称性和结构的不同表面图案。通过使用功能分子在二维(2D)表面上纳米器件制造中的主要挑战是实现从分子被动和自发吸附到选定组织的分子模式。

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