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Unprecedented Sulfone-Functionalized Metal-Organic Frameworks and Gas-Sorption Properties

机译:前所未有的砜功能化金属有机骨架和吸气性能

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摘要

Porous, metal–organic frameworks (MOFs) or coordination polymers (PCPs) represent a unique class of crystalline open framework solids with unprecedented structures, diverse chemical composition, adjustable pores sizes, large surface areas and pore volumes.[1] These hybrid porous materials result from molecular self-assembly reactions between metal ions or clusters and bridging multidentade organic lig- ACHTUNGTRENUNGands, usually performed under hydroACHTUNGTRENUNG(solvo)thermal conditions. The combination of accessible porosity and framework functionalities in these solids, arising from both the inorganic and organic component, results in unique properties that could lead to applications in technologically important fields including gas storage,[2] separation[3] and catalysis.
机译:多孔的金属有机骨架(MOF)或配位聚合物(PCP)代表一类独特的结晶开放骨架固体,具有前所未有的结构,不同的化学组成,可调节的孔径,大表面积和孔体积。[1]这些杂化多孔材料是由金属离子或簇之间的分子自组装反应和桥连多齿有机配体ACHTUNGTRENUNGands产生的,通常在加氢ACHTUNGTRENUNG(溶剂)热条件下进行。由无机和有机成分产生的这些固体中可及的孔隙度和骨架功能的结合,产生了独特的性能,可导致其在重要技术领域中的应用,包括气体存储,[2]分离[3]和催化。

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