Trapping Reactive Metal–Carbene Complexes by a Bis-Pocket Porphyrin:X-ray Crystal Structures of Ru=CHCO_2Et andtranstRu(CHR)(CO)]Species and Highly Selective Carbenoid Transfer Reactions

Qing-Hai Deng; Jian Chen; Jie-Sheng Huang; Stephen Sin-Yin Chui; Nianyong Zhu; Guang-Yu Li; Chi-Ming Che

首页> 外文期刊>Chemistry: A European journal >Trapping Reactive Metal–Carbene Complexes by a Bis-Pocket Porphyrin:X-ray Crystal Structures of Ru=CHCO_2Et andtranstRu(CHR)(CO)]Species and Highly Selective Carbenoid Transfer Reactions

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Trapping Reactive Metal–Carbene Complexes by a Bis-Pocket Porphyrin:X-ray Crystal Structures of Ru=CHCO_2Et andtranstRu(CHR)(CO)]Species and Highly Selective Carbenoid Transfer Reactions

机译：双口袋卟啉捕获活性金属-碳配合物：Ru = CHCO_2Et和transtRu（CHR）（CO）]种类的X射线晶体结构及高度选择性的类胡萝卜素转移反应

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We gratefully acknowledge the financial support by The University ofHong Kong (University Development Fund), Hong Kong ResearchGrants Council (HKU 1/CRF/08), and the University Grants Council ofHKSAR (Area of Excellence Scheme: AoE 10/01P). Q.H. Deng thanksthe Croucher Foundation of Hong Kong for a postgraduate studentship.

机译：非常感谢香港大学（大学发展基金），香港研究资助局（HKU 1 / CRF / 08）和香港特别行政区大学教育资助局（卓越计划：AoE 10 / 01P）的财政支持。问邓小平感谢香港裘rou基金会的研究生奖学金。

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《Chemistry: A European journal》 |2009年第41期|共6页
作者
Qing-Hai Deng; Jian Chen; Jie-Sheng Huang; Stephen Sin-Yin Chui; Nianyong Zhu; Guang-Yu Li; Chi-Ming Che;
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正文语种 eng
中图分类应用化学;
关键词
carbenoids; porphyrinoids; reactiveintermediates; ruthenium; structure elucidation;

机译：类胡萝卜素;卟啉类;反应性中间体;钌;结构解析;

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1. Trapping Reactive Metal–Carbene Complexes by a Bis-Pocket Porphyrin:X-ray Crystal Structures of Ru=CHCO_2Et andtranstRu(CHR)(CO)]Species and Highly Selective Carbenoid Transfer Reactions [J] . Qing-Hai Deng, Jian Chen, Jie-Sheng Huang, Chemistry: A European journal . 2009,第41期

机译：双口袋卟啉捕获活性金属-碳配合物：Ru = CHCO_2Et和transtRu（CHR）（CO）]种类的X射线晶体结构及高度选择性的类胡萝卜素转移反应
2. Ruthenium(Ⅱ) Porphyrin Quinoid Carbene Complexes: Synthesis, Crystal Structure, and Reactivity toward Carbene Transfer and Hydrogen Atom Transfer Reactions [J] . Wang Hai-Xu, Wan Qingyun, Wu Kai, Journal of the American Chemical Society . 2019,第22期

机译：钌（Ⅱ）卟啉奎单甲苯复合物：合成，晶体结构和对卡贝转移和氢原子转移反应的反应性
3. Reactivities governed by a single metal atom M in mixed-metal highnuclearity clusters having [Ru5M(C)] core (M = Co, Rh, Pd): Site-nonselective, site-selective, and chemo-selective variations in the SO2-trapping reactions [J] . Nakajima T, Konomoto H, Ogawa H, Journal of Organometallic Chemistry . 2007,第22期

机译：具有[Ru5M（C）]核（M = Co，Rh，Pd）的混合金属高核簇中的单个金属原子M控制的反应性：SO2捕集中的位点非选择性，位点选择性和化学选择性变化反应
4. Reaction of nitric oxide species with metal centered macrocyclic complexes: (1) Catalytic oxygen atom transfer reaction using water-soluble ferric porphyrin complexes and nitrite ion, and (2) Nitric oxide reaction with derivatized cupric cyclam complexes [D] . Khin, Chosu 2008

机译：一氧化氮物质与以金属为中心的大环配合物的反应：（1）使用水溶性三价铁卟啉配合物和亚硝酸根离子的催化氧原子转移反应，以及（2）衍生化的铜环素配合物的一氧化氮反应
5. Coupling of Fischer carbene complexes with conjugated enediynes featuring radical traps; Novel structure and reactivity features of chromium complexed arene diradical species [O] . Yi Zhang, Tareq Irshaidat, Haixia Wang, -1

机译：Fischer卡宾配合物与具有自由基陷阱的共轭二炔的偶联反应；铬配合物芳烃双自由基物种的新型结构和反应活性
6. Ruthenium(II) Porphyrin Quinoid Carbene Complexes: Synthesis, Crystal Structure, and Reactivity toward Carbene Transfer and Hydrogen Atom Transfer Reactions [O] . -1

机译：钌（II）卟啉奎单甲苯复合物：合成，晶体结构和对卡贝转移和氢原子转移反应的反应性
7. Chemistry of Polynuclear Metal Complexes with Bridging Carbene or Carbyne Ligands. Part 63. Synthesis of Eight-Membered-Ring Metallacycles: X-Ray Crystal Structures [R] . Elliott, G. P., Howard, J. A., Mise, T., 1987

机译：具有桥接卡宾或卡宾配体的多核金属配合物的化学。第63部分。八元环金属环的合成：X射线晶体结构

Trapping Reactive Metal–Carbene Complexes by a Bis-Pocket Porphyrin:X-ray Crystal Structures of Ru=CHCO_2Et andtranstRu(CHR)(CO)]Species and Highly Selective Carbenoid Transfer Reactions

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