The reactivity of a silacyclopentadienylidene towards aldehydes: Silole ring expansion and the formation of base-stabilized silacyclohexadienones

Gao Y.; Hu H.; Cui C.

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The reactivity of a silacyclopentadienylidene towards aldehydes: Silole ring expansion and the formation of base-stabilized silacyclohexadienones

机译：硅杂环戊二烯对醛的反应性：硅环扩环和碱稳定的硅环己二酮的形成

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Tossing aldehydes into the ring: The reaction of a silacyclopentadienylidene with aldehydes leads to C=O bond cleavage with the formation of base-stabilized silanones and cyclopropanation of the adjacent C=C bond, followed by silole ring expansion to give silicon analogues of cyclohexadienones (see scheme).

机译：将醛丢入环中：硅杂环戊二烯与醛的反应导致C = O键断裂，形成碱稳定的硅烷酮，相邻C = C键环丙烷化，然后进行硅环扩环，得到环己二酮的硅类似物参见方案）。

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《Chemistry: A European journal》 |2011年第32期|共4页
作者
Gao Y.; Hu H.; Cui C.;
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正文语种 eng
中图分类应用化学;
关键词
aldehydes; ring expansion; silanones; silicon; siloles; silylenes;

机译：醛;扩环;硅酮;硅;硅;硅;

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1. The reactivity of a silacyclopentadienylidene towards aldehydes: Silole ring expansion and the formation of base-stabilized silacyclohexadienones [J] . Gao Y., Hu H., Cui C. Chemistry: A European journal . 2011,第32期

机译：硅杂环戊二烯对醛的反应性：硅环扩环和碱稳定的硅环己二酮的形成
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5. Siloles Bearing Coordination-Active 2,5-Substituents: Synthesis, Reactivity, Structural and Spectral Properties [D] . Carroll, James B., II 2013

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The reactivity of a silacyclopentadienylidene towards aldehydes: Silole ring expansion and the formation of base-stabilized silacyclohexadienones

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