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首页> 外文期刊>Chemistry: A European journal >Vine-twining polymerization: amylose twines around polyethers to form amylose-polyether inclusion complexes
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Vine-twining polymerization: amylose twines around polyethers to form amylose-polyether inclusion complexes

机译：藤蔓缠绕聚合：直链淀粉缠绕在聚醚周围，形成直链淀粉-聚醚包合物

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摘要

In this paper, we describe a new polymerization manner termed as "vine-twining polymerization" to produce amylose-polymer inclusion complexes. The polymerization was achieved by an enzymatic polymerization of alpha-D-glucose-1-phosphate monomer catalyzed by phosphorylase in the presence of polyTHF as a guest polymer. The structure the product was determined by X-ray powder diffraction and ~1H NMR measurements to be the inclusion complex. The formation process of the inclusion complexes during the polymerization was also evaluated. Furthermore, the formation of the inclusion complexes by this polymerization method by using polyTHFs with various M_(n~S) and end groups, as well as other polyethers as the guest polymers, was examined.
机译：在本文中，我们描述了一种新的聚合方式，称为“葡萄缠结聚合”以生产直链淀粉-聚合物包合物。在作为客体聚合物的聚THF的存在下，通过磷酸化酶催化的α-D-葡萄糖-1-磷酸单体的酶促聚合来实现聚合。通过X射线粉末衍射和〜1H NMR测量确定产物的结构为包合物。还评估了聚合过程中包合物的形成过程。此外，研究了使用具有各种M_（n〜S）和端基的聚THF以及其他聚醚作为客体聚合物通过这种聚合方法形成的包合物。

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