Free radical reactivity of mono- and dichlorosilylene with muonium

Percival P.W.; Brodovitch J.-C.; Mozafari M.; Mitra A.; West R.; Ghadwal R.S.; Azhakar R.; Roesky H.W.

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Free radical reactivity of mono- and dichlorosilylene with muonium

机译：一氯和二氯甲硅烷基与mu的自由基反应性

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The H atom analogue muonium (Mu) has been used to explore the free radical reactivity of two novel chlorosilylenes. Spectroscopic and computational investigations show that Mu adds to the silicon in the NHC-stabilised dichlorosilylene. In contrast, Mu reacts at the carbon of a siladiazirene ring in the monochlorosilylene. Muon and Cl hyperfine constants are consistent with flipping of the Si-Cl bond from one side of the ring to the other.

机译：H原子类似物（（Mu）已用于探索两种新型氯代甲硅烷基的自由基反应性。光谱和计算研究表明，Mu在NHC稳定的二氯甲硅烷基中添加了硅。相反，Mu在单氯甲硅烷基中的硅二氮杂烯环的碳上反应。 Muon和Cl超精细常数与Si-Cl键从环的一侧翻转到另一侧一致。

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《Chemistry: A European journal》 |2011年第43期|共4页
作者
Percival P.W.; Brodovitch J.-C.; Mozafari M.; Mitra A.; West R.; Ghadwal R.S.; Azhakar R.; Roesky H.W.;
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正文语种 eng
中图分类应用化学;
关键词
heterocycles; muonium; radicals; silicon; silylenes;

机译：杂环;mu;自由基;硅;亚甲硅烷基;

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专利

1. Free radical reactivity of mono- and dichlorosilylene with muonium [J] . Percival P.W., Brodovitch J.-C., Mozafari M., Chemistry: A European journal . 2011,第43期

机译：一氯和二氯甲硅烷基与mu的自由基反应性
2. How do strain and steric interactions affect the reactions of aromatic compounds with free radicals? Characterization of the radicals formed by muonium addition to p-Xylene and [2.2]paracyclophane by DFT calculations and muon spin spectroscopy [J] . McKenzie I., Scheuermann R., Sedlak K. The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2012,第29期

机译：应变和空间相互作用如何影响芳族化合物与自由基的反应？通过DFT计算和μ自旋光谱法表征由mu加成对二甲苯和[2.2]对环环烷形成的自由基
3. Free Radical Formation in Supercritical CO2,Using Muonium as a Probe and Implication for H Atom Reaction with Ethene [J] . P.Cormier, D.J.Arseneau, J.C.Brodovitch The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2008,第20期

机译：超临界CO 2中自由基的形成，以Mu为探针，探讨乙烯与H原子反应的意义
4. FREE RADICAL CHEMISTRY OF THE MONO- AND DIHALONITROMETHANES [C] . William J. Cooper, Stephen P. Mezyk, S. Kirkham Cole American Chemical Society Division of Environmental Chemistry Symposium . 2008

机译：单卤硝基甲烷的自由基化学
5. Muonium kinetics and free radical formation in solutions of fullerenes. [D] . Kecman, Sonja. 2004

机译：富勒烯溶液中的动力学和自由基形成。
6. Theoretical study on the electronic structural properties and reactivity of a series of mono- di- tri- and tetrachlorothiophenes as well as corresponding radical cation forms as monomers for conducting polymers [O] . Hossein Shirani IL Beigi, Saeed Jameh-Bozorghi 2011

机译：关于一系列单二三和四氯噻吩以及相应的自由基阳离子形式作为导电聚合物单体的电子结构性质和反应性的理论研究
7. Muonium kinetics and intramolecular motion of muonium-substituted free radicals [O] . Yu Dake 1989

机译：mu取代的自由基的on动力学和分子内运动

Free radical reactivity of mono- and dichlorosilylene with muonium

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