C_3-symmetric Pt_3Pd_3 purine vases based on a metal coordination motif involving the pyrimidinic N1 and N3 sites

Ibá?ez S.; Albertí F.M.; Sanz Miguel P.J.; Lippert B.

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C_3-symmetric Pt_3Pd_3 purine vases based on a metal coordination motif involving the pyrimidinic N1 and N3 sites

机译：基于涉及嘧啶N1和N3位点的金属配位基序的C_3对称Pt_3Pd_3嘌呤花瓶

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摘要

Vase-shaped hexanuclear (Pt_3Pd_3) complexes with 9-alkylhypoxanthinate ligands bridging three (en)Pd~(II) units through N1 and N3 sites are reported, which bind ClO_4~- ions in their cavities, albeit not in strictly analogous ways. The structural differences reflect the flexibility of the host cation and may even be relevant to the mechanism of ClO_4~- incorporation into the host or ejection from it.

机译：据报道，花瓶形的六核（Pt_3Pd_3）与通过N1和N3位点桥接三个（en）Pd〜（II）单元的9-烷基次黄嘌呤配体形成了络合物，尽管它们不是严格相似的方式，但它们在腔中结合了ClO_4〜离子。结构上的差异反映了主体阳离子的柔韧性，甚至可能与ClO_4掺入主体或从主体中弹出的机理有关。

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来源
《Chemistry: A European journal》 |2011年第34期|共5页
作者
Ibá?ez S.; Albertí F.M.; Sanz Miguel P.J.; Lippert B.;
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原文格式 PDF
正文语种 eng
中图分类应用化学;
关键词
anion binding; host-guest systems; metallacycles; purine nucleobase;

机译：阴离子结合;客体系统;金属环化合物;嘌呤核碱基;

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1. C_3-symmetric Pt_3Pd_3 purine vases based on a metal coordination motif involving the pyrimidinic N1 and N3 sites [J] . Ibá?ez S., Albertí F.M., Sanz Miguel P.J., Chemistry: A European journal . 2011,第34期

机译：基于涉及嘧啶N1和N3位点的金属配位基序的C_3对称Pt_3Pd_3嘌呤花瓶
2. Influence of Noncovalent Interactions on Uracil Tautomer Selection:Coordination of Both N1 and N3 Uracilate to the Same Metal in the Solid State [J] . Inmaculada Escorihuela, Larry R.Falvello, Milagros Tomas, Crystal growth & design . 2004,第4期

机译：非共价相互作用对尿嘧啶互变异构体选择的影响：尿嘧啶N1和N3两者在固态中与同一金属的配位
3. PtII coordination to N1 of 9-methylguanine: Why it facilitates binding of additional metal ions to the purine ring [J] . Müller B., Shen W.-Z., Sanz Miguel P.J., Chemistry: A European journal . 2011,第36期

机译：PtII与9-甲基鸟嘌呤N1的配位：为什么它促进其他金属离子与嘌呤环的结合
4. Environmetal issues involving the international siting of wood product manufacturing facilities [C] . Robert P.Newman, Mr.James R.Rabe Environmental conference exhibit . 1997

机译：涉及木制品生产设施国际选址的环境问题
5. Nonenzymatic oligomerization of RNA by TNA templates, and, Isoguanine-modified thrombin aptamers, and, An antiparallel purine·purine DNA duplex, and, Synthesis and enzymatic polymerization of FNA on DNA templates, and, Thermodynamics and luminescence of novel metallo-DNA base-pairs. [D] . Heuberger, Benjamin David. 2007

机译：TNA模板，异鸟嘌呤修饰的凝血酶适体，反平行嘌呤·嘌呤DNA双链体以及FNA在DNA模板上的合成和酶促聚合，以及新型金属DNA碱基的热力学和发光，通过RNA的非酶促寡聚化对。
6. Importance of halide involving interactions at Hoogsteen sites in supramolecular architectures of some coordination metal complexes of N6-benzyl/furfuryl adenine [O] . Samson Jegan Jennifer, Packianathan Thomas Muthiah, Duraiswamy Tamilselvi 2014

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7. C3-symmetric Pt3Pd3 purine vases based on a metal coordination motif involving the pyrimidinic N1 and N3 sites [O] . Ibáñez Susana, Sanz Miguel Pablo J. 2013

机译：基于涉及嘧啶N1和N3位点的金属配位基序的C3对称Pt3Pd3嘌呤花瓶

C_3-symmetric Pt_3Pd_3 purine vases based on a metal coordination motif involving the pyrimidinic N1 and N3 sites

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