Well-defined air-stable palladium HASPO complexes for efficient Kumada-Corriu cross-couplings of (Hetero)aryl or alkenyl tosylates

Ackermann L.; Kapdi A.R.; Fenner S.; Kornhaab C.; Schulzke C.

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Well-defined air-stable palladium HASPO complexes for efficient Kumada-Corriu cross-couplings of (Hetero)aryl or alkenyl tosylates

机译：定义明确的空气稳定钯HASPO配合物，可实现（杂）芳基或烯基甲苯磺酸盐的有效Kumada-Corriu交叉偶联

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Palladium complexes of representative heteroatom-substituted secondary phosphine oxide (HASPO) preligands were synthesized and fully characterized, including X-ray crystal structure analysis. Importantly, these well-defined complexes served as highly efficient catalysts for Kumada-Corriu cross-coupling reactions of aryl, alkenyl, and even heteroaryl tosylates. Particularly, an air-stable catalyst derived from inexpensive PinP(O)H displayed a remarkably high catalytic efficacy, which resulted in cross-couplings at low catalyst loadings under exceedingly mild reaction conditions with ample scope.

机译：合成并充分表征了代表性的杂原子取代的次膦氧化物（HASPO）预配体的钯配合物，包括X射线晶体结构分析。重要的是，这些定义明确的络合物可作为Kumada-Corriu芳基，烯基乃至杂芳基甲苯磺酸酯的交叉偶联反应的高效催化剂。特别地，衍生自廉价的PinP（O）H的空气稳定的催化剂表现出显着的催化功效，这导致在足够温和的反应条件下，在足够的范围内，在低催化剂负载下的交叉偶联。

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《Chemistry: A European journal》 |2011年第10期|共7页
作者
Ackermann L.; Kapdi A.R.; Fenner S.; Kornhaab C.; Schulzke C.;
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原文格式 PDF
正文语种 eng
中图分类应用化学;
关键词
catalysis; cross-coupling; ligand; palladium; tosylate;

机译：催化;交叉偶联;配体;钯;甲苯磺酸酯;

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1. Well-defined air-stable palladium HASPO complexes for efficient Kumada-Corriu cross-couplings of (Hetero)aryl or alkenyl tosylates [J] . Ackermann L., Kapdi A.R., Fenner S., Chemistry: A European journal . 2011,第10期

机译：定义明确的空气稳定钯HASPO配合物，可实现（杂）芳基或烯基甲苯磺酸盐的有效Kumada-Corriu交叉偶联
2. Well-Defined Air-Stable Palladium HASPO Complexes for Efficient Kumada–Corriu Cross-Couplings of (Hetero)Aryl or Alkenyl Tosylates [J] . Prof. Dr. Lutz Ackermann, Dr. Anant R. Kapdi, Dipl.-Chem. Sabine Fenner, Chemistry - A European Journal . 2011,第10期

机译：定义良好的空气稳定钯HASPO配合物，用于（杂）芳基或烯基甲苯磺酸盐的高效Kumada-Corriu交叉偶联
3. The Highly Efficient Suzuki-Miyaura Cross-Coupling of (Hetero)aryl Chlorides and (Hetero)arylboronic Acids Catalyzed by "Bulky-yet-Flexible" Palladium-PEPPSI Complexes in Air [J] . ChemCatChem . 2018,第2期

机译：（杂）芳基氯化物和（杂）芳基硼酸的高效铃木 - 氨基酰胺催化在空气中“庞大且柔性”钯 - 蛋白酶络合物催化
4. Palladium-Catalyzed gamma -Selective Cross-Coupling of Potassium Allyltrifluoroborates with Aryl and 1-Alkenyl Bromides [C] . Yasunori Yamamoto, Shingo Takada, Norio Miyaura Symposium on Organometallic Chemistry . 2006

机译：钯催化的丙烷与芳基和1-链烯基溴硼硼酸钾的丙烷的交叉偶联
5. Part I. Synthesis of aryl or alkenyl sulfides via copper(I) mediated cross-coupling of disulfides and aryl alkenyl halides. Part II. Design of molecular switches: Novel 2,3-bisheteroaryl-quinone switch and its applications. [D] . Deng, Xiaohu. 2001

机译：第一部分。经由铜（I）介导的二硫化物和芳基烯基卤化物的交叉偶联合成芳基或烯基硫。第二部分分子开关的设计：新颖的2,3-双双芳基醌开关及其应用。
6. Metallated Aziridines for Cross-Coupling with Aryl and Alkenyl Halides via Palladium Catalysis [O] . John M. Nelson, Edwin Vedejs -1

机译：通过钯催化金属化的氮丙啶类交叉耦合与芳基和卤代烯烃
7. Asymmetric cross-coupling of alkyl, alkenyl and (hetero)aryl nucleophiles with racemic allyl halides [O] . Philipp Schäfer, Mireia Sidera, Thomas Palacin, 2017

机译：用外消旋烯丙基卤化物的烷基，链烯基和（杂）芳基亲核试剂的不对称交叉偶联
8. Aryl Bis(triflates) in Palladium (0) Cross-Coupling Reactions. Synthesis ofPolyphenyl-Alkynyl, Alkenyl, and Aryl Ethers [R] . Wright, M. E. 1991

机译：钯（0）交叉偶联反应中的芳基双（三氟甲磺酸酯）。聚苯基 - 炔基，烯基和芳基醚的合成

Well-defined air-stable palladium HASPO complexes for efficient Kumada-Corriu cross-couplings of (Hetero)aryl or alkenyl tosylates

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