Multi-path magnetic relaxation of mono-dysprosium(III) single-molecule magnet with extremely high barrier

Watanabe A.; Yamashita A.; Nakano M.; Yamamura T.; Kajiwara T.

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Multi-path magnetic relaxation of mono-dysprosium(III) single-molecule magnet with extremely high barrier

机译：具有极高势垒的mono（III）单分子磁体的多径磁弛豫

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A large magnetic anisotropy was achieved around the Dy~(III) ion, and a single-molecule magnet behavior has been observed up to 35 K for the dinuclear complex Dy~(III)-Zn~(II). The magnetic relaxation occurs through three different pathways depending on the temperature and the presence of an external dc field (see scheme).

机译：在Dy〜（III）离子周围实现了较大的磁各向异性，双核配合物Dy〜（III）-Zn〜（II）的单分子磁体行为高达35K。取决于温度和外部直流场的存在，磁弛豫通过三种不同的途径发生（请参阅方案）。

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《Chemistry: A European journal》 |2011年第27期|共5页
作者
Watanabe A.; Yamashita A.; Nakano M.; Yamamura T.; Kajiwara T.;
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原文格式 PDF
正文语种 eng
中图分类应用化学;
关键词
dysprosium; lanthanides; ligand field anisotropy; magnetic properties; tunnelling relaxation;

机译：dy;镧系元素;配体各向异性;磁性能;隧道弛豫;

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1. Multi-path magnetic relaxation of mono-dysprosium(III) single-molecule magnet with extremely high barrier [J] . Watanabe A., Yamashita A., Nakano M., Chemistry: A European journal . 2011,第27期

机译：具有极高势垒的mono（III）单分子磁体的多径磁弛豫
2. 2LnIII₂} Single-Molecule Magnets]]> [J] . Kuduva R. Vignesh, Stuart K. Langley, Boujemaa Moubaraki, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2018,第3期

机译：<！[CDATA [了解五核液中磁性弛豫的机制{Mn 静脉> mn iii _{2 ln III < 亚> 2 }单分子磁铁]]>}
3. Magnetic Relaxation of Single-Molecule Magnets in an External Magnetic Field: An Ising Dimer of a Terbium(III)–Phthalocyaninate Triple-Decker Complex [J] . Dr. Keiichi Katoh, Prof. Takashi Kajiwara, Prof. Motohiro Nakano, Chemistry - A European Journal . 2011,第1期

机译：外部磁场中单分子磁体的磁弛豫：:( III）-酞菁酞菁三重复合物的Ising二聚体
4. The local magnetic properties of Mn_6~(III) Cr~(III)~(3+) and Fe_6~(III) Cr~(III)~(3+) single-molecule magnets deposited on surfaces studied by spin-polarized photoemission and XMCD with circularly polarized synchrotron radiation [C] . U. Heinzmann, A. Helmstedt, N. Dohmeier, ICPEAC . 2014

机译：Mn_6〜（III）Cr〜（III）〜（3+）和Fe_6〜（III）Cr〜（III）〜（3+）单分子磁铁的局部磁性特性沉积在旋转的表面上 - 具有圆极化同步辐射的循环光曝光和XMCD
5. Quantum magnetic phenomena in zero-dimensional through three-dimensional manganese(III)-based single-molecule magnets. [D] . Feng, Patrick Lulick. 2010

机译：通过基于三维锰（III）的单分子磁体在零维中产生量子磁性现象。
6. Hydroxide-bridged five-coordinate DyIII single-molecule magnet exhibiting the record thermal relaxation barrier of magnetization among lanthanide-only dimers [O] . Jin Xiong, Hai-Yan Ding, Yin-Shan Meng, 2017

机译：氢氧化物桥接的五坐标DyIII单分子磁体在仅镧系元素的二聚体中表现出创纪录的磁化热弛豫势垒
7. Understanding the Mechanism of Magnetic Relaxation in Pentanuclear {MnIVMnIII2LnIII2} Single-Molecule Magnets [O] . Kuduva R. Vignesh, Stuart K. Langley, Boujemaa Moubaraki, 2018

机译：理解五核液中磁性松弛机制{MNIVMNIII2LNIII2}单分子磁铁

Multi-path magnetic relaxation of mono-dysprosium(III) single-molecule magnet with extremely high barrier

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