Pd-catalyzed multiple C-H functionalization to construct biologically active compounds from aryl aldoxime ethers with arenes

Thirunavukkarasu V.S.; Cheng C.-H.

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Pd-catalyzed multiple C-H functionalization to construct biologically active compounds from aryl aldoxime ethers with arenes

机译：钯催化的多个C-H官能化反应可从芳基醛肟醚与芳烃中构建具有生物活性的化合物

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摘要

Functional fluorenones: Aromatic aldoxime ethers react with unactivated arenes catalyzed by palladium complexes to give biologically active fluoren-9-ones (see scheme). Multiple C-H bond activation and an oxidative cyclization are involved in the reaction.

机译：功能性芴酮：芳族醛肟肟醚与钯配合物催化的未活化芳烃反应，生成具有生物活性的芴9-酮（参见方案）。该反应涉及多个C-H键活化和氧化环化。

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《Chemistry: A European journal》 |2011年第52期|共4页
作者
Thirunavukkarasu V.S.; Cheng C.-H.;
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正文语种 eng
中图分类应用化学;
关键词
C-H activation; cyclization; fluorenone; oxime ether; palladium;

机译：碳氢活化;环化;芴酮;肟醚;钯;

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专利

1. Pd-catalyzed multiple C-H functionalization to construct biologically active compounds from aryl aldoxime ethers with arenes [J] . Thirunavukkarasu V.S., Cheng C.-H. Chemistry: A European journal . 2011,第52期

机译：钯催化的多个C-H官能化反应可从芳基醛肟醚与芳烃中构建具有生物活性的化合物
2. Efficient solvent- and temperature-tuned access to aldoxime ethers and phenolic functions by Pd-catalyzed C-O cross-coupling of aldoximes with aryl bromides and bromo-chalcones [J] . Reeta, Rangarajan T. M., Kaushik Kumar, New Journal of Chemistry . 2020,第4期

机译：通过PD催化的醛氧化物与芳溴化物和溴 - 硫氨酸的醛氧化物的C-O交叉偶联的高效溶剂和温度调节对醛氧化物醚和酚类功能的进入
3. Combining Ru-Catalyzed C-H Functionalization with Pd-Catalyzed Asymmetric Allylic Alkylation: Synthesis of 3-Allyl-3-aryl Oxindole Derivatives from Aryl alpha-Diazoamides [J] . Yamamoto Kosuke, Qureshi Zafar, Tsoung Jennifer, Organic letters . 2016,第19期

机译：结合Ru催化的C-H功能化与Pd催化的不对称烯丙基烷基化：由芳基α-重氮酰胺合成3-烯丙基-3-芳基羟吲哚衍生物
4. Synthesis and plant anti-viral activity of 4-quinazoline aryl oxime or aliphatic aldoxime oxime ethers [C] . Hui-Ying Li, Run-Qiu Huang, Xin Liu, 9th Japan-China Symposium on Pesticide Science October 26-28, 1998 Tian Jin China . 1998

机译：4-喹唑啉芳基肟或脂族醛肟肟醚的合成及植物抗病毒活性
5. Development of Ortho C-H Functionalization of Arenes Using Modifiable Silicon Tethered Directing Group. [D] . Sarkar, Dhruba. 2016

机译：使用可修饰的硅链引导基团开发芳烃的邻位C-H功能化。
6. tBu3P-Coordinated 2-Phenylaniline-Based Palladacycle Complex As Precatalyst for Pd-Catalyzed Coupling Reactions of Aryl Halides with Polyfluoroarenes via C-H Activation Strategy [O] . Hong-Hai Zhang, Jie Dong, Qiao-Sheng Hu -1

机译：tBu3P配位的2-苯基苯胺基Palladacycle配合物作为C-H活化策略Pd催化卤代芳烃与多氟芳烃偶联反应的前催化剂
7. Pd-Catalyzed Aryl C-H Imidation with Arene as the Limiting Reagent [O] . Boursalian, G., Ngai, M., Hojczyk, K., 2013

机译：用芳烃作为限制剂的pd催化的芳基C-H酰亚胺化
8. Polyhedral Oligomeric Silsesquioxane-Functionalized Perfluorocyclobutyl Aryl Ether Polymers: An Overview of the Synthesis and Properties of Polyhedral Oligomeric Silsesquioxanes (POSS) Functionalized with Perfluorocyclobutyl (PFCB) Aryl Ether Polymer Ble [R] . Iacono, S. T., Budy, S. M., Smith, J. D., 2007

机译：多面体低聚倍半硅氧烷 - 官能化全氟环丁基芳基醚聚合物：用全氟环丁基（pFCB）芳基醚聚合物共聚物功能化的多面体低聚倍半硅氧烷（pOss）的合成和性质概述

Pd-catalyzed multiple C-H functionalization to construct biologically active compounds from aryl aldoxime ethers with arenes

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