Remarkably effective phosphanes simply with a PPh_2 moiety: Application to Pd-Catalysed cross-coupling reactions for tetra-ortho-substituted biaryl syntheses

So C.M.; Chow W.K.; Choy P.Y.; Lau C.P.; Kwong F.Y.

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Remarkably effective phosphanes simply with a PPh_2 moiety: Application to Pd-Catalysed cross-coupling reactions for tetra-ortho-substituted biaryl syntheses

机译：仅具有PPh_2部分的非常有效的膦：在Pd催化的四邻位取代联芳基合成的交叉偶联反应中的应用

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Chemical equation presented Expanding the horizons of ArPPh_2: New applications of triarylphosphane ligands are presented. The Pd-L1 and Pd-L2 complexes offer exceptionally high activity in Suzuki-Miyaura cross-couplings of aryl chlorides. The extremely congested synthesis of tetraortho-substituted biaryl compounds is achieved for the first time by simply using triarylphosphane ligands.

机译：提出化学方程式扩展ArPPh_2的视野：提出了三芳基膦烷配体的新应用。 Pd-L1和Pd-L2络合物在Suzuki-Miyaura芳基氯化物的交叉偶联中具有极高的活性。仅通过使用三芳基膦配体，首次实现了四邻位取代的联芳基化合物的极为拥挤的合成。

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《Chemistry: A European journal》 |2010年第27期|共6页
作者
So C.M.; Chow W.K.; Choy P.Y.; Lau C.P.; Kwong F.Y.;
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原文格式 PDF
正文语种 eng
中图分类应用化学;
关键词
Biaryls; Cross-coupling; Palladium; Phosphane ligands; Suzuki-Miyaura coupling;

机译：联芳基;交叉偶联;钯;磷配体;铃木-宫浦偶联;

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1. Remarkably effective phosphanes simply with a PPh_2 moiety: Application to Pd-Catalysed cross-coupling reactions for tetra-ortho-substituted biaryl syntheses [J] . So C.M., Chow W.K., Choy P.Y., Chemistry: A European journal . 2010,第27期

机译：仅具有PPh_2部分的非常有效的膦：在Pd催化的四邻位取代联芳基合成的交叉偶联反应中的应用
2. "Computationally Assisted Mechanistic Investigation and Development of Pd-Catalyzed Asymmetric Suzuki Miyaura and Negishi Cross-Coupling Reactions for Tetra-ortho-Substituted Biaryl Synthesis (vol 8, pg 10190, 2018) [J] . Patel Nitinchandra D., Sieber Joshua D., Tcyrulnikov Sergei, ACS catalysis . 2019,第2期

机译：“计算辅助机械调查和PD催化不对称铃木Miyaura和Negishi交叉偶联反应的机械调查和开发，对Tetra-邻替代的前芳基合成（Vol 8，PG 10190,2018）
3. Computationally Assisted Mechanistic Investigation and Development of Pd-Catalyzed Asymmetric Suzuki-Miyaura and Negishi Cross-Coupling Reactions for Tetra-ortho-Substituted Biaryl Synthesis [J] . Patel Nitinchandra D., Sieber Joshua D., Tcyrulnikov Sergei, ACS catalysis . 2018,第11期

机译：计算辅助机械调查和促型非对称铃木Miyaura和Negishi交叉偶联反应对Tetra-右替代的芳基合成的影响
4. Suzuki-Miyaura Reaction Using Biphenylene-containing Ruthenocenylphosphine (R-Phos): Synthesis of Tetra-ortho-substituted Biaryl from Aryl Chloride [C] . Takashi Hoshi, Ippei Saitoh, Toshio Suzuki Symposium on Organometallic Chemistry . 2007

机译：铃木宫果酰胺反应使用含有联苯的钌烯基（R-PHOS）的反应：从芳氯的芳基的四右替代的芳丙齐芳基
5. An application of the intramolecular Heck reaction: A new strategy in the synthesis of Hasubanan alkaloids. Preparation of unsymmetrical biaryls via the Stille cross-coupling reaction: Synthesis of highly functional intermediates towards the synthesis of vindoline. [D] . Frank, Anthony Joseph. 2002

机译：分子内Heck反应的应用：合成Hasubanan生物碱的新策略。通过Stille交叉偶联反应制备不对称的联芳基：合成高功能性中间体，合成长春新碱。
6. Computationally Assisted Mechanistic Investigation and Development of Pd-Catalyzed Asymmetric Suzuki-Miyaura and Negishi Cross-Coupling Reactions for Tetra-ortho-Substituted Biaryl Synthesis [O] . Nitinchandra Dahyabhai Patel, Joshua D. Sieber, Sergei Tcyrulnikov, -1

机译：Pd催化的不对称Suzuki-Miyaura和Neshishi交叉偶联反应的计算辅助机理研究与开发用于四邻位取代联芳基的合成
7. Remarkably effective phosphanes simply with a PPh2 moiety : application to Pd-catalysed cross-coupling reactions for Tetra-ortho-substituted Biaryl Syntheses [O] . So CM, Chow WK, Choy PY, 2010

机译：仅具有PPh2部分的非常有效的膦：应用于四邻位取代的联芳基合成的Pd催化的交叉偶联反应

Remarkably effective phosphanes simply with a PPh_2 moiety: Application to Pd-Catalysed cross-coupling reactions for tetra-ortho-substituted biaryl syntheses

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