Enantioselective reduction of ketones and imines catalyzed by (CN-Box)Re~V-oxo complexes

Nolin K.A.; Ahn R.W.; Kobayashi Y.; Kennedy-Smith J.J.; Toste F.D.

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Enantioselective reduction of ketones and imines catalyzed by (CN-Box)Re~V-oxo complexes

机译：（CN-Box）Re〜V-oxo配合物催化酮和亚胺的对映选择性还原

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The development and application of chiral, non-racemic Re~V-oxo complexes to the enantioselective reduction of prochiral ketones is described. In addition to the enantioselective reduction of prochiral ketones, we report the application of these complexes to 1) a tandem Meyer-Schuster rearrangement/reduction to access enantioenriched allylic alcohols and 2) the enantioselective reduction of imines.

机译：描述了手性，非外消旋的Re〜V-氧代复合物在手性酮的对映选择性还原中的开发和应用。除了手性酮的对映体选择性还原，我们还报道了这些复合物的应用：1）串联Meyer-Schuster重排/还原来获得对映体富集的烯丙醇，以及2）亚胺的对映体选择性还原。

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《Chemistry: A European journal》 |2010年第31期|共8页
作者
Nolin K.A.; Ahn R.W.; Kobayashi Y.; Kennedy-Smith J.J.; Toste F.D.;
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正文语种 eng
中图分类应用化学;
关键词
Enantioselective reduction; Hydrosilylation; Rearrangement; Rhenium;

机译：对映选择性还原;氢化硅烷化;重排;R;

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专利

1. Enantioselective reduction of ketones and imines catalyzed by (CN-Box)Re~V-oxo complexes [J] . Nolin K.A., Ahn R.W., Kobayashi Y., Chemistry: A European journal . 2010,第31期

机译：（CN-Box）Re〜V-oxo配合物催化酮和亚胺的对映选择性还原
2. Homogeneous Enantioselective Catalysis in a Continuous-Flow Microreactor: Highly Enantioselective Borohydride Reduction of Ketones Catalyzed by Optically Active Cobalt Complexes [J] . Takuo Hayashi, Satoshi Kikuchi, Yukako Asano Organic process research & development . 2012,第6期

机译：连续流微反应器中的均相对映选择性催化：旋光活性钴配合物催化酮的高对映选择性硼氢化还原
3. Optically active #beta#-ketoiminato cobalt(II) complexes as highly efficient catalysts in enantioselective borohydride reduction of ketones, imines, and #alpha#,#beta#-unsaturated carboxylates [J] . Tohru Yamada, Takushi Nagata, Taketo Ikeno, Inorganica Chimica Acta . 1999,第1期

机译：旋光性＃beta＃-酮亚胺酸钴（II）络合物作为对映选择性硼氢化物还原酮，亚胺和#alpha＃，＃beta＃-不饱和羧酸盐的高效催化剂
4. REDUCTION OF KETONES CATALYZED BY OXO-COMPLEXES USING CARBOHYDRATES AS CHIRAL LIGANDS [C] . Ivania Cabrita, Sara C. A. Sousa, Ana C. Fernandes International Carbohydrate Symposium . 2013

机译：使用碳水化合物作为手性配体，通过氧气复合物催化的酮还原
5. Development of Iridium-Catalyzed Allylation Reactions of Ketones and Imines and Nickel-Catalyzed and Titanium-Mediated Cross-Coupling Reactions of N-Chloroamines. [D] . Barker, Timothy James. 2011

机译：酮和胺的铱催化的烯丙基化反应的发展以及镍催化的钛和钛介导的氯胺的交叉偶联反应的发展。
6. Enantioselective Reduction of Ketones and Imines Catalyzed by (CN-Box)Re(V)-Oxo Complexes [O] . Kristine A. Nolin, Richard W. Ahn, Yusuke Kobayashi, -1

机译：通过（CN-BOX）RE（V）-OxO复合物催化酮和癌症的致力选择性降低
7. Enantioselective Reduction of Ketones and Imines Catalyzed by (CN-Box)ReV-Oxo Complexes [O] . Kristine A. Nolin, Richard W. Ahn, Yusuke Kobayashi, 2010

机译：通过（CN-BOX）Rev-Oxo复合物催化酮和癌症的对致映选择性降低

Enantioselective reduction of ketones and imines catalyzed by (CN-Box)Re~V-oxo complexes

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