Unraveling the mechanism of the singlet oxygen ene reaction: Recent computational and experimental approaches

Alberti M.N.; Orfanopoulos M.

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Unraveling the mechanism of the singlet oxygen ene reaction: Recent computational and experimental approaches

机译：揭示单线态氧烯反应的机理：最新的计算和实验方法

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The mechanism of the singlet oxygen ene reaction has been a subject of renewed interest within the last few years. The main question being whether this reaction proceeds through a concerted mechanism or if it involves discrete intermediates. In general, the majority of experimental and computational studies support a traditional stepwise mechanism involving a perepoxidelike intermediate. In this minireview we highlight the most prominent and recent theoretical, as well as experimental results relating to the challenging mechanism of the singlet oxygen ene oxyfunctionalization.

机译：在过去几年中，单线态氧烯反应的机理引起了人们的关注。主要问题是该反应是否通过协调机制进行，还是涉及离散的中间体。通常，大多数实验和计算研究都支持涉及过氧化物类中间体的传统逐步机理。在这份小型回顾中，我们重点介绍了与单线态氧烯氧官能化的挑战性机理有关的最著名和最新的理论以及实验结果。

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《Chemistry: A European journal》 |2010年第31期|共8页
作者
Alberti M.N.; Orfanopoulos M.;
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正文语种 eng
中图分类应用化学;
关键词
Computational chemistry; Cyclopropyl probes; Reaction mechanisms; Singlet oxygen; Stereoselectivity;

机译：计算化学;环丙基探针;反应机理;单氧;立体选择性;

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1. Unraveling the mechanism of the singlet oxygen ene reaction: Recent computational and experimental approaches [J] . Alberti M.N., Orfanopoulos M. Chemistry: A European journal . 2010,第31期

机译：揭示单线态氧烯反应的机理：最新的计算和实验方法
2. Comparison of the singlet oxygen ene reactions of cyclic versus acyclic β,γ-unsaturated ketones: an experimental and computational study [J] . Axel G. Griesbeck, Bernd Goldfuss, Matthias Leven Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2013,第23期

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Unraveling the mechanism of the singlet oxygen ene reaction: Recent computational and experimental approaches

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