Synthesis of Monocarbenepalladium(0) Complexes and Their Catalytic Behavior in Cross-Coupling Reactions of Aryldiazonium Salts

Kumaravel Selvakumar; Alexander Zapf; Anke Spannenberg; Matthias Beller

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Synthesis of Monocarbenepalladium(0) Complexes and Their Catalytic Behavior in Cross-Coupling Reactions of Aryldiazonium Salts

机译：单碳烯钯（0）配合物的合成及其在芳族重氮盐交叉偶联反应中的催化行为

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The first monocarbenepalladium(0) complexes with benzoquinone and naphthoquinone as additional ligands have been prepared. As demonstrated by NMR spectroscopy and X-ray analysis, the complexes show a unique coordination mode giving quinone-bridged dimers. The monocarbenepalladium(0) complexes allow efficient cross-coupling reactions of aryldiazonium salts with olefins (Heck reaction) and arylboronic acids (Suzuki reaction).

机译：已经制备了具有苯醌和萘醌作为另外的配体的第一单碳烯钯（0）配合物。如NMR光谱和X射线分析所证明的，该配合物显示出独特的配位模式，可提供醌桥二聚体。单碳烯钯（0）配合物可实现芳基重氮盐与烯烃的有效交叉偶联反应（Heck反应）和芳基硼酸（Suzuki反应）。

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来源
《Chemistry: A European journal》 |2002年第17期|共6页
作者
Kumaravel Selvakumar; Alexander Zapf; Anke Spannenberg; Matthias Beller;
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原文格式 PDF
正文语种 eng
中图分类化学;应用化学;
关键词
carbenes; heck reaction; homogeneous catalysis; palladium; suzuki reaction;

机译：卡宾;赫克反应;均相催化;钯;铃木反应;

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1. Synthesis of Monocarbenepalladium(0) Complexes and Their Catalytic Behavior in Cross-Coupling Reactions of Aryldiazonium Salts [J] . Kumaravel Selvakumar, Alexander Zapf, Anke Spannenberg, Chemistry: A European journal . 2002,第17期

机译：单碳烯钯（0）配合物的合成及其在芳族重氮盐交叉偶联反应中的催化行为
2. Cross-Coupling Reactions of Aryldiazonium Salts with Allylsilanes under Merged Gold/Visible-Light Photoredox Catalysis [J] . Akram Manjur O., Mali Pramod S., Patil Nitin T. Organic letters . 2017,第12期

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Synthesis of Monocarbenepalladium(0) Complexes and Their Catalytic Behavior in Cross-Coupling Reactions of Aryldiazonium Salts

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