Retention of configuration in the nucleophilic substitution reactions of some nine-membered ansa derivatives of cyclotriphosphazatriene

Besli S; Coles SJ; Davies DB; Hursthouse MB; Ibisoglu H; Kilic A; Shaw RA

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Retention of configuration in the nucleophilic substitution reactions of some nine-membered ansa derivatives of cyclotriphosphazatriene

机译：环三磷氮杂三烯的某些九元ansa衍生物亲核取代反应中的构型保留

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摘要

X-ray crystallographic evidence shows that nucleophilic substitution reactions of two different types of cyclophosphazene derivatives with relatively rigid nine-membered ansa rings leads to the first demonstration of retention of configuration in these molecular systems.

机译：X射线晶体学证据表明，两种不同类型的环磷腈衍生物具有相对刚性的九元ansa环的亲核取代反应导致这些分子系统中构型的保留首次得到证明。

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《Chemistry: A European journal》 |2004年第19期|共6页
作者
Besli S; Coles SJ; Davies DB; Hursthouse MB; Ibisoglu H; Kilic A; Shaw RA;
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正文语种 eng
中图分类化学;
关键词
ansa rings; configuration determination; nucleophilic substitution; phosphazenes; retention of configuration; RAY CRYSTAL-STRUCTURES; CYCLOPHOSPHAZENES; PHOSPHAZENES; SPERMIDINE; SPIRANSA;

机译：ansa环;构型确定;亲核取代;磷腈;构型保留;RAY晶体结构;环磷酰胺;磷酸酯;亚精胺;螺旋藻;

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Retention of configuration in the nucleophilic substitution reactions of some nine-membered ansa derivatives of cyclotriphosphazatriene

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