• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Chemistry: A European journal >Molecular Logic Gates Based on Pentacyanoferrate Complexes:From Simple Gates to Three-Dimensional Logic Systems
【24h】

Molecular Logic Gates Based on Pentacyanoferrate Complexes:From Simple Gates to Three-Dimensional Logic Systems

机译：基于五氰基铁酸盐配合物的分子逻辑门：从简单的门到三维逻辑系统

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

The article presents new aspects of reactivity of two pentacyano-ferrates:[Fe(CN)_5NO]~(2-)and [Fe(CN)_5-N(O)SR]~(3-).The dependence of ther-modynamic functions on cations was found for the reaction between nitro-prusside and thiolate.The thermody-namic data are interpreted in terms of ion pairing and changes in the solva-tion shell of the cations.It was found that the reaction enthalpies and entropies depend strongly on the cation radius.The reaction volume in turn is strongly affected by the structure and properties of the hydration shell.Careful data analysis allowed the contribution of partial cation dehydration to the total reaction volume to be determined.The experimental results were also interpreted in terms of chemical logic gates.Complex logic systems were built from a number of cells containing a switching compound arranged in different geometric patterns.Increasing the dimensionality of these arrangements leads to really complex logic systems containing up to 20 AND and OR logic gates.The system is capable of processing up to 16 bits of input data.
机译：本文介绍了两种五氰基高铁酸盐[Fe（CN）_5NO]〜（2-）和[Fe（CN）_5-N（O）SR]〜（3-）的反应性的新方面。发现硝基普鲁司苷与硫醇盐之间的反应具有阳离子的动力学功能。热力学数据用离子对和阳离子溶解壳的变化来解释，发现反应的焓和熵取决于反应体积受水合壳结构和性能的影响很大，通过仔细的数据分析可以确定部分阳离子脱水对总反应体积的影响，并解释了实验结果。复杂逻辑系统是由许多包含以不同几何图案排列的开关化合物的单元构成的，增加这些排列的尺寸会导致真正复杂的逻辑系统，包含多达20个AND和OR逻辑门。该系统能够处理多达16位的输入数据。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号