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首页> 外文期刊>Chemistry: A European journal >Anatomy of long-lasting love affairs with lithium carbenoids: Past and present status and future prospects
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Anatomy of long-lasting love affairs with lithium carbenoids: Past and present status and future prospects

机译：锂类胡萝卜素持久恋爱关系的解剖：过去和现在的状况以及未来的前景

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"Figure Presentation" After a long adolescence, the chemistry of lithium carbenoids has currently been entering its maturity bringing a dowry of a more in-depth and less empirical knowledge of the structure and configurational stability of such double-faced intermediates; this, thanks in particular to the synergistic and harmonic cooperation between calculations and the most modern NMR techniques now at our disposal. Such knowledge has stimulated the development of fruitful stereoselective applications in the field of organic synthesis, providing in addition a rationale to observed selectivities. Such aspects together with the role played by aggregation and solvation on the structure-reactivity relationship are highlighted throughout this Minireview with selected examples extracted from recent literature.
机译：“图呈现”经过长时间的青春期，锂类胡萝卜素的化学性质目前已进入成熟阶段，从而使人们对这类双面中间体的结构和构型稳定性有了更深入的了解，而对这些方面的了解较少。这尤其要归功于计算与目前最先进的NMR技术之间的协同和谐波协作。此类知识刺激了有机合成领域卓有成效的立体选择性应用的发展，此外还为观察到的选择性提供了理论依据。这些方面以及聚集和溶剂化对结构-反应性关系所起的作用在本微型综述中都突出了，这些例子选自最近的文献。

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