A concise route to α'-methoxy-γ-pyrones and verticipyrone based upon the desymmetrization of αα'-dimethoxy-γ-pyrone

De Paolis M.; Rosso H.; Henrot M.; Prandi C.; Herouville F.D.; Maddaluno J.

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A concise route to α'-methoxy-γ-pyrones and verticipyrone based upon the desymmetrization of αα'-dimethoxy-γ-pyrone

机译：基于αα'-二甲氧基-γ-吡喃酮的脱对称性，获得α'-甲氧基-γ-吡喃酮和维替吡酮的简洁途径

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Two steps is the rule: A concise synthesis of versatile α-methoxy-γ-pyrones (see scheme) is described that uses an innovative desymmetrization of α α-dimethoxy-γ-pyrone relying upon conjugate addition of nucleophiles. This new strategy is applied to the preparation of αmethyl and α-carboxaldehyde-α-methoxy-γ- pyrones and to a short synthesis of verticipyrone.

机译：规则是两个步骤：描述了一种通用的α-甲氧基-γ-吡喃酮的简洁合成方法（请参见方案），该方法利用创新的αα-二甲氧基-γ-吡喃酮的脱对称作用，依赖于亲核试剂的共轭加成。该新策略适用于α甲基和α-甲醛-α-甲氧基-γ-吡喃酮的制备以及维替吡酮的短合成。

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来源
《Chemistry: A European journal》 |2010年第37期|共4页
作者
De Paolis M.; Rosso H.; Henrot M.; Prandi C.; Herouville F.D.; Maddaluno J.;
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原文格式 PDF
正文语种 eng
中图分类应用化学;
关键词
Desymmetrization; Heterocycles; Metathesis; Pyrones; Synthetic methods;

机译：非对称化;杂环;易位;吡喃酮;合成方法;

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1. A concise route to α'-methoxy-γ-pyrones and verticipyrone based upon the desymmetrization of αα'-dimethoxy-γ-pyrone [J] . De Paolis M., Rosso H., Henrot M., Chemistry: A European journal . 2010,第37期

机译：基于αα'-二甲氧基-γ-吡喃酮的脱对称性，获得α'-甲氧基-γ-吡喃酮和维替吡酮的简洁途径
2. A Concise Route to ′-Methoxy--pyrones and Verticipyrone Based Upon the Desymmetrization of ,′-Dimethoxy--pyrone [J] . Dr. Michaeuml, l De Paolis, Helegrave, Chemistry - A European Journal . 2010,第37期

机译：基于'，-二甲氧基-吡喃酮的不对称化，一种精确的合成'-甲氧基-吡喃酮和维替吡酮的途径
3. Concise Synthesis of a PateamineA Analogue with In Vivo Anticancer Activity Based on an Iron-Catalyzed Pyrone Ring Opening/Cross-Coupling [J] . Zhuo Chun-Xiang, Fuerstner Alois Angewandte Chemie . 2016,第20期

机译：简化基于铁催化的催力龙环开口/交叉耦合的体内抗癌活性的Pateaminea类似物的合成
4. Synthesis, Luminescence Properties, and Synthetic Application of Multi-Substituted 2-Pyrones Including a Carbon-Indium Bond [C] . Tetsuji Yata, Yuji Kita, Yoshihiro Nishimoto 日本化学会春季年会講演予稿集 . 2018

机译：多取代的2-吡喃酮的合成，发光性能和合成施用，包括碳铟键
5. Synthesis of 2-Pyrone Containing Products and Hibiscone C [D] . Qu, Yang. 2018

机译：合成含有2-吡喃酮的产品和HibIsce C.
6. 26-Dicyano-4-pyrone as a Novel and Multifarious BuildingBlock for the Synthesis of 26-Bis(hetaryl)-4-pyrones and 26-Bis(hetaryl)-4-pyridinols [O] . Dmitrii L. Obydennov, *, Alena E. Simbirtseva, 2020

机译：26-二甘薯-4-吡喃酮作为新颖和多种建筑用于合成26-双（Hetaryl）-4-吡喃酮和26-双（Hetaryl）-4-吡啶醇的嵌段
7. Concise Synthesis of a Pateamine A Analogue with In Vivo Anticancer Activity Based on an Iron-Catalyzed Pyrone Ring Opening/Cross-Coupling [O] . Zhuo C., Fürstner A. 2016

机译：基于铁催化的吡咯环开环/交叉偶联简明合成具有体内抗癌活性的帕特明a类似物
8. Quantum Chemistry: Concerning the Excited States Occurring in the Photochemical Reactions of alpha -Pyrone, gamma -Pyrone, Coumarin, and Chromone [R] . Bouanini, H., Gayoso, J. 1973

机译：量子化学：关于α-吡喃酮，γ-吡喃酮，香豆素和色酮的光化学反应中发生的激发态

A concise route to α'-methoxy-γ-pyrones and verticipyrone based upon the desymmetrization of αα'-dimethoxy-γ-pyrone

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