A Convergent General Strategy for the Functionalized 2-Aryl Cycloalkyl-Fused Chromans: Intramolecular Hetero-Diels–Alder Reactions of ortho-Quinone Methides

Jumreang Tummatorn; Somsak Ruchirawat; Poonsakdi Ploypradith

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A Convergent General Strategy for the Functionalized 2-Aryl Cycloalkyl-Fused Chromans: Intramolecular Hetero-Diels–Alder Reactions of ortho-Quinone Methides

机译：功能化的2-芳基环烷基融合的色氨酸的聚合通用策略：邻醌醌的分子内杂Diels-Alder反应

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Chroman is a core structure of flavonoids, which have been shown to exhibit a wide array of biological activities.[1] Palodesangren C (1; Scheme 1), a natural Diels–Alder Scheme 1. Examples of 2-arylcycloalkyl-fused chromans (shown with relative stereochemistry)

机译：Chroman是类黄酮的核心结构，已显示出其广泛的生物活性。[1] Palodesangren C（1;方案1），一种自然的Diels-Alder方案1. 2-芳基环烷基稠合色氨酸的例子（以相对立体化学显示）

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《Chemistry: A European journal》 |2010年第5期|共4页
作者
Jumreang Tummatorn; Somsak Ruchirawat; Poonsakdi Ploypradith;
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正文语种 eng
中图分类应用化学;
关键词
chromans; cycloaddition; cyclization; quinone methides; stereoselective reactions;

机译：苯并二氢吡喃;环加成;环化;甲基苯醌;立体选择性反应;

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1. A Convergent General Strategy for the Functionalized 2-Aryl Cycloalkyl-Fused Chromans: Intramolecular Hetero-Diels–Alder Reactions of ortho-Quinone Methides [J] . Jumreang Tummatorn, Somsak Ruchirawat, Poonsakdi Ploypradith Chemistry: A European journal . 2010,第5期

机译：功能化的2-芳基环烷基融合的色氨酸的聚合通用策略：邻醌醌的分子内杂Diels-Alder反应
2. Synthesis of C4-C5 Cycloalkyl-Fused and C6-Modified Chromans via ortho-Quinone Methides [J] . Tangdenpaisal Kassrin, Chuayboonsong Kanokpish, Sukjarean Patchaya, Chemistry, an Asian journal . 2015,第4期

机译：邻醌醌法合成C4-C5环烷基和C6-修饰的三价铬
3. Intramolecular Aza-Diels-Alder Reactions of ortho-Quinone Methide Imines: Rapid, Catalytic, and Enantioselective Assembly of Benzannulated Quinolizidines [J] . Kretzschmar Martin, Hofmann Fabian, Moock Daniel, Angewandte Chemie . 2018,第17期

机译：邻醌甲基酰亚胺的分子内AZA-DIELS - alder反应：Benzannization喹硫吡啶的快速，催化和致力化组装
4. Asymmetric Hetero-Diels–Alder Reaction of Non-activated Substrates Utilizing Dual Activation of Cationic Fe(III) Lewis Acid and Chiral Br?nsted Acid [C] . Rei Tomifuji, Takuya Kurahashi, Seijiro Matsubara 日本化学会春季年会講演予稿集 . 2018

机译：利用阳离子Fe（III）Lewis酸和手性β的非活化基材的不对称异质蛋白 - 桤木反应。
5. I. Studies toward the formal synthesis of (+)-aldosterone. II. Type 2 intramolecular hetero Diels-Alder reaction and the discovery of a novel tandem hetero Diels-Alder reaction. [D] . Bear, Brian Richard. 2001

机译：I.对（+）-醛固酮的形式合成的研究。二。 2型分子内杂Diels-Alder反应和新型串联杂Diels-Alder反应的发现。
6. Synthesis of the hexacyclic triterpene core of the jujuboside saponins via tandem Wolff rearrangement–intramolecular ketene hetero-Diels–Alder reaction [O] . Rashad R. Karimov, Derek S. Tan, David Y. Gin -1

机译：通过串联Wolff重排-分子内烯酮杂Diels-Alder反应合成枣核苷皂苷的六环三萜核
7. Brnsted Acid-Catalyzed, Diastereo- and Enantioselective, Intramolecular Oxa-Diels-Alder Reaction of ortho-Quinone Methides and Unactivated Dienophiles [O] . -1

机译：Brnsted酸催化，非对疗法和对映射性，分子内的氧气氧化物 - 阳离子反应邻醌 - 醌甲基溴酸和未活化的辅酶

A Convergent General Strategy for the Functionalized 2-Aryl Cycloalkyl-Fused Chromans: Intramolecular Hetero-Diels–Alder Reactions of ortho-Quinone Methides

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