Versatile anion-π interactions between halides and a conformationally rigid bis(tetraoxacalix[2]arene[2]triazine) cage and their directing effect on molecular assembly

Wang D.-X.; Wang Q-Q.; Han Y.; Wang Y.; Huang Z-T.; Wang M.-X.

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Versatile anion-π interactions between halides and a conformationally rigid bis(tetraoxacalix[2]arene[2]triazine) cage and their directing effect on molecular assembly

机译：卤化物与构象刚性双（tetraoxacalix [2] arene [2] triazine）笼之间的多功能阴离子-π相互作用及其对分子组装的指导作用

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Interactive halides: Bis(tetraoxacalix[2]arene[2]triazine), a conformationally rigid cage molecule of three V-shaped electron-deficient clefts, forms 1:1 complexes with fluoride (361 M~(-1)), chloride (146 M~(-1)) and bromide (95 M~(-1)) in acetonitrile. Different anion-π interactions along with multiple hydrogen bonding, halogen bonding and lone-pair-electrons-π interactions directed the formation of different molecular assemblies (an example is shown here).

机译：相互作用卤化物：Bis（tetraoxacalix [2] arene [2] triazine），一种构象刚性的笼状分子，由三个V形缺电子裂隙构成，与氟化物（361 M〜（-1）），氯化物形成1：1络合物含146 M〜（-1））和溴化物（95 M〜（-1））的乙腈溶液。不同的阴离子-π相互作用以及多个氢键，卤素键和孤对电子-π相互作用指导了不同分子组件的形成（此处显示了一个示例）。

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《Chemistry: A European journal》 |2010年第44期|共5页
作者
Wang D.-X.; Wang Q-Q.; Han Y.; Wang Y.; Huang Z-T.; Wang M.-X.;
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原文格式 PDF
正文语种 eng
中图分类应用化学;
关键词
anions; calixarenes; halides; host-guest systems; molecular assembly; pi interactions;

机译：阴离子;杯芳烃;卤化物;客体-客体系统;分子组装;π相互作用;

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1. Versatile anion-π interactions between halides and a conformationally rigid bis(tetraoxacalix[2]arene[2]triazine) cage and their directing effect on molecular assembly [J] . Wang D.-X., Wang Q-Q., Han Y., Chemistry: A European journal . 2010,第44期

机译：卤化物与构象刚性双（tetraoxacalix [2] arene [2] triazine）笼之间的多功能阴离子-π相互作用及其对分子组装的指导作用
2. Halide Recognition by Tetraoxacalix[2]arene[2]triazine Receptors : Concurrent Noncovalent Halide-π and Lone-pair-π Interactions in Host-Halide-Water Ternary Complexes [J] . De-Xian Wang, Qi-Yu Zheng, Qi-Qiang Wang Angewandte Chemie . 2008,第39期

机译：Tetraoxacalix [2] arene [2] triazine受体识别卤化物：主体卤化物-水三元络合物中同时发生的非共价卤化物-π和孤对-π相互作用。
3. Halide Recognition by Tetraoxacalix[2]arene[2]triazine Receptors : Concurrent Noncovalent Halide-π and Lone-pair-π Interactions in Host-Halide-Water Ternary Complexes [J] . De-Xian Wang, Qi-Yu Zheng, Qi-Qiang Wang Angewandte Chemie . 2008,第39期

机译：Tetraoxacalix [2] arene [2] triazine受体识别卤化物：主体卤化物-水三元络合物中同时发生的非共价卤化物-π和孤对-π相互作用。
4. Self-Assembly Directed Organization of Fullerene-Bisporphyrins into Supramolecular Donut Structures for Excited State Charge Stabilization [C] . Ruben Caballero, Pilar de la Cruz, Enrique Orti, Pacific Rim Meeting on Electrochemical and Solid-State Science . 2020

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6. SPE-UHPLC-FLD Method for the Simultaneous Determination of Five Anthraquinones in Human Urine Using Mixed-Mode Bis(tetraoxacalix2arene2triazine) Modified Silica as Sorbent [O] . Kai Hu, Yonghui Qiao, Zhifen Deng, 2017

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机译：银双（噻嗪唑啉基）甲烷化学和银 - 硫相互作用中的阴离子和溶剂定向组装

Versatile anion-π interactions between halides and a conformationally rigid bis(tetraoxacalix[2]arene[2]triazine) cage and their directing effect on molecular assembly

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