Tuning the spin states of two apical iron(II) ions in the trigonalbipyramidal [{Fe~(II)(μ-bpt)_3}_2Fe _3~(II)(μ_3-O)]~(2+) cations through the choice of anions

Bao X.; Leng J.-D.; Meng Z.-S.; Lin Z.; Tong M.-L.; Nihei M.; Oshio H.

首页> 外文期刊>Chemistry: A European journal >Tuning the spin states of two apical iron(II) ions in the trigonalbipyramidal [{Fe~(II)(μ-bpt)_3}_2Fe _3~(II)(μ_3-O)]~(2+) cations through the choice of anions

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Tuning the spin states of two apical iron(II) ions in the trigonalbipyramidal [{Fe~(II)(μ-bpt)_3}_2Fe _3~(II)(μ_3-O)]~(2+) cations through the choice of anions

机译：通过选择调整三角双锥体[{Fe〜（II）（μ-bpt）_3} _2Fe _3〜（II）（μ_3-O）]〜（2+）阳离子中两个顶铁离子的自旋态阴离子

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(Figure Presented) Polinuclear Fe~(II) Clusters: A new family of {Fe_5} cluster compounds formulated with [{Fe~(II)(μ-bpt) _3}_2Fe_3~(II)(μ3O)]X_2 have been synthesised from the solvothermal reactions of 4-amino-3,5-bis(pyridine-2- yl)-1,2,4-triazole with-ferrous salts. The spin states of the two apical iron(II) ions in the cationic pentanuclear (Fe_5} clusters can be tuned to give the high-spin states by the [Fe_2OCl_6] ~(2-) anion and the low-spin states by SCN-/ClO _4-/I- (see scheme).

机译：（呈现的图）多核Fe〜（II）簇：合成了由[{Fe〜（II）（μ-bpt）_3} _2Fe_3〜（II）（μ3O）] X_2配制的{Fe_5}簇新化合物由4-氨基-3，5-双（吡啶-2-基）-1，2，4-三唑与亚铁盐的溶剂热反应得到。可以调整阳离子五核（Fe_5}簇中两个顶端铁（II）离子的自旋态，使其由[Fe_2OCl_6]〜（2-）阴离子提供高自旋态，并通过SCN-调整为低自旋态/ ClO _4- / I-（请参阅方案）。

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来源
《Chemistry: A European journal》 |2010年第21期|共6页
作者
Bao X.; Leng J.-D.; Meng Z.-S.; Lin Z.; Tong M.-L.; Nihei M.; Oshio H.;
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正文语种 eng
中图分类应用化学;
关键词
Cluster compounds; Iron; Magnetic properties; Spin transitions triazoles;

机译：团簇化合物;铁;磁性;自旋跃迁三唑;

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1. Tuning the spin states of two apical iron(II) ions in the trigonalbipyramidal [{Fe~(II)(μ-bpt)_3}_2Fe _3~(II)(μ_3-O)]~(2+) cations through the choice of anions [J] . Bao X., Leng J.-D., Meng Z.-S., Chemistry: A European journal . 2010,第21期

机译：通过选择调整三角双锥体[{Fe〜（II）（μ-bpt）_3} _2Fe _3〜（II）（μ_3-O）]〜（2+）阳离子中两个顶铁离子的自旋态阴离子
2. Tuning the Spin States of Two Apical Iron(II) Ions in a Pentanuclear Iron(II) Cluster Helicate through the Choice of Anions [J] . Kuan-Hui Fan, Qi Huang, Xiao-Yu Fang, Crystals . 2018,第3期

机译：通过选择阴离子调节五核铁（II）簇螺旋中两个顶端铁（II）离子的自旋态
3. Tuning the Spin States of Two Apical Iron(II) Ions in a Pentanuclear Iron(II) Cluster Helicate through the Choice of Anions [J] . Kuan-Hui Fan, Qi Huang, Xiao-Yu Fang, Crystals . 2018,第3期

机译：通过选择阴离子调节五核铁（II）簇螺旋中两个顶端铁（II）离子的自旋态
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Tuning the spin states of two apical iron(II) ions in the trigonalbipyramidal [{Fe~(II)(μ-bpt)_3}_2Fe _3~(II)(μ_3-O)]~(2+) cations through the choice of anions

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