Metal–Organic-Framework-Based Catalyst for Highly Efficient H_2 Generation from Aqueous NH_3BH_3 Solution

Yaoqi Li; Lei Xie; Yan Li; Jie Zheng; Xingguo Li

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Metal–Organic-Framework-Based Catalyst for Highly Efficient H_2 Generation from Aqueous NH_3BH_3 Solution

机译：基于金属有机骨架的催化剂，可从NH_3BH_3水溶液中高效生成H_2

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Metal–organic frameworks (MOFs) have attracted much attention as they have been widely investigated for hydrogen storage, gas separation and catalysis.[1–8] The microporous porosity, the large specific surface area and, especially, the controllable framework have made MOFs superior to traditional inorganic porous materials such as zeolites and activated carbon.[2, 9, 10] MOFs contain abundant uniform microporous pores and channels, which offer convenient conditions for different molecules to access the interior metal sites and organic ligands.

机译：金属有机骨架（MOF）受到广泛关注，因为它们已被广泛研究用于储氢，气体分离和催化。[1-8]微孔孔隙，较大的比表面积，尤其是可控的骨架使MOF成为可能。 [2，9，10] MOF包含丰富的均匀微孔和通道，这为不同分子进入内部金属位点和有机配体提供了便利的条件。

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《Chemistry: A European journal》 |2009年第36期|共4页
作者
Yaoqi Li; Lei Xie; Yan Li; Jie Zheng; Xingguo Li;
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正文语种 eng
中图分类应用化学;
关键词
framework; pattern demonstrates; Aqueous NH3BH3 Solution;

机译：框架;模式演示;NH3BH3水溶液;

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专利

1. Metal–Organic-Framework-Based Catalyst for Highly Efficient H_2 Generation from Aqueous NH_3BH_3 Solution [J] . Yaoqi Li, Lei Xie, Yan Li, Chemistry: A European journal . 2009,第36期

机译：基于金属有机骨架的催化剂，可从NH_3BH_3水溶液中高效生成H_2
2. Superporous P(2-hydroxyethyl methacrylate) cryogel-M (M:Go, Ni, Cu) composites as highly effective catalysts in H_2 generation from hydrolysis of NaBH_4 and NH_3BH_3 [J] . Fahriyc Seven, Nurettin Sahiner International journal of hydrogen energy . 2014,第28期

机译：超孔P（2-甲基丙烯酸羟乙酯）冷冻凝胶-M（M：Go，Ni，Cu）复合物可高效水解NaBH_4和NH_3BH_3产生H_2
3. Promoted H_2 generation from NH_3BH_3 thermal dehydrogenation catalyzed by metal-organic framework based catalysts [J] . Li Y., Song P., Zheng J., Chemistry: A European journal . 2010,第35期

机译：金属有机骨架催化剂催化NH_3BH_3热脱氢促进H_2生成
4. Transition metals on carbon aerogels as catalysts in the degradation of azo - dyes in aqueous solutions [C] . Filipa Duarte, Francisco J. Maldonado-Hodar, Luis M. Madeira, CARBON'09;Annual world conference on carbon;World conference on carbon . 2009

机译：碳气凝胶上的过渡金属在水溶液中偶氮染料降解中的催化作用。
5. Design and synthesis of ferrocenylmethylphosphines for transition metal catalysis: From highly active cross -coupling catalysts to highly efficient addition reaction catalysts [D] . Lu, Yong 2007

机译：用于过渡金属催化的二茂铁基甲基膦的设计与合成：从高活性的交叉偶联催化剂到高效的加成反应催化剂
6. Layered Titanate H2Nd2Ti3O10 Intercalated With n-Butylamine: A New Highly Efficient Hybrid Photocatalyst for Hydrogen Production From Aqueous Solutions of Alcohols [O] . Ivan A. Rodionov, Elizaveta A. Maksimova, Artem Y. Pozhidaev, 2019

机译：层状钛酸盐H2ND2TI3O10与正丁胺相嵌合：一种新的高效杂交光催化剂用于醇水溶液的氢气产生
7. Noncovalently Linked Metallacarboranes on Functionalized Magnetic Nanoparticles as Highly Efficient, Robust, and Reusable Photocatalysts in Aqueous Medium [O] . -1

机译：在官能化磁性纳米粒子上的非共价连接的金属吡啶硼烷作为水性介质中高效，鲁棒和可重复使用的光催化剂
8. Rhenium Catalysis:Ⅰ. Hydrogenation and Hydroformylation Using Rhenium Carbonyl Compounds. Ⅱ. Hydrogenation Using Catalysts Obtained from the Reduction of Perrhenates with Metals in Aqueous Solution [R] . T. G. Selin 1957

机译：铼催化：Ⅰ。使用铼羰基化合物进行氢化和加氢甲酰化。 Ⅱ。在水溶液中用金属还原高铼酸盐获得催化剂的氢化

Metal–Organic-Framework-Based Catalyst for Highly Efficient H_2 Generation from Aqueous NH_3BH_3 Solution

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