Rational Monomer Design towards 2D Polymers: Synthesis of a Macrocycle with Three 1,8-Anthrylene Units

Patrick Kissel; A. Dieter Schluter; Junji Sakamoto

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Rational Monomer Design towards 2D Polymers: Synthesis of a Macrocycle with Three 1,8-Anthrylene Units

机译：面向2D聚合物的合理单体设计：具有三个1,8-蒽单元的大环的合成

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One monomer unit thick (or better: thin) covalent networks with a translational periodicity are referred to as 2D polymers, and these are still on the wish list of synthetic chemistry.[1] Such structures have been proposed repeatedly,[ 2] but have never been made and unequivocally proven. Limited numbers of 2D polymers are available from Nature. They are usually obtained by exfoliation of graphite (graphene)[3] or inorganic lamellar crystals like montmorillonite. Rational synthetic avenues to 2D polymers are still awaiting to be developed. A couple of years back we started a research project aimed at providing organic chemical solutions to this burning question.

机译：具有翻译周期性的一个单体单元厚的（或更好的是：薄的）共价网络被称为2D聚合物，而这些仍然在合成化学的愿望清单中。[1]这种结构已经被反复提出[2]，但从未被制造出来并且得到明确的证明。有限数量的2D聚合物可从Nature公司获得。它们通常是通过剥落石墨（石墨烯）[3]或无机层状晶体（如蒙脱石）而获得的。二维聚合物的合理合成途径仍在等待开发。几年前，我们启动了一个研究项目，旨在为这个迫切的问题提供有机化学解决方案。

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《Chemistry: A European journal》 |2009年第36期|共6页
作者
Patrick Kissel; A. Dieter Schluter; Junji Sakamoto;
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正文语种 eng
中图分类应用化学;
关键词
2D polymers; Rational Monomer Design; montmorillonite;

机译：二维聚合物;理性单体设计;蒙脱土;

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1. Rational Monomer Design towards 2D Polymers: Synthesis of a Macrocycle with Three 1,8-Anthrylene Units [J] . Patrick Kissel, A. Dieter Schluter, Junji Sakamoto Chemistry: A European journal . 2009,第36期

机译：面向2D聚合物的合理单体设计：具有三个1,8-蒽单元的大环的合成
2. Towards 2D and 3D Coordination Polymers: Synthesis of Shape-Persistent Star Monomers with 2,2':6',2"-Terpyridin-4'-y1 Units at the Periphery [J] . Thomas Bauer, A. Dieter Schluter, Junji Sakamoto Synlett . 2010,第6期

机译：朝向2D和3D配位聚合物：在周边的2,2'：6'，2英寸 - 吡啶-4'-Y1单元合成形状持久的星形单体
3. Rational design of an amorphous poly(2-oxazoline) with a low glass-transition temperature: Monomer synthesis, copolymerization, and properties [J] . Kempe K., Jacobs S., Lambermont-Thijs H.M.L., Macromolecules . 2010,第9期

机译：玻璃化转变温度低的非晶态聚（2-恶唑啉）的合理设计：单体合成，共聚和性能
4. 1-Amino-4,5-8-naphthalenetricarboxylic acid-1,8-lactam-4,5-imide-containing macrocycles: Synthesis, molecular modeling and polymerization [C] . PATRICIA PONCE, LIOUDMILA FOMINA, PATRICIA GARCIA, International symposium on polyimides and other high temperature polymers: Synthesis, characterization and applications . 2003

机译：1-氨基-4,5-8-萘甲酸-1,8-内酰胺-4,5-酰亚胺的宏杂种：合成，分子建模和聚合
5. Control of stereochemistry in vinyl polymers via rational monomer design: Cyclopolymerization of chiral bis(methacrylates). [D] . Zheng, Shiying. 1997

机译：通过合理的单体设计控制乙烯基聚合物中的立体化学：手性双（甲基丙烯酸酯）的环聚合。
6. Synthesis of Stable and Soluble One-Handed Helical Homopoly(substituted acetylene)s without the Coexistence of Any Other Chiral Moieties via Two-Step Polymer Reactions in Membrane State: Molecular Design of the Starting Monomer [O] . Yunosuke Abe, Toshiki Aoki, Hongge Jia, 2012

机译：通过膜态的两步聚合反应合成稳定且可溶的单手螺旋均聚（取代的乙炔）而无其他手性部分的合成：起始单体的分子设计
7. Rational design of an amorphous poly(2-oxazoline) with a low glass-transition temperature: Monomer synthesis, copolymerization, and properties [O] . Kristian Kempe, Stefan Jacobs, Hanneke M. L. Lambermont-thijs, 2014

机译：合理设计具有低玻璃化转变温度的无定形聚（2-恶唑啉）：单体合成，共聚合和性质

Rational Monomer Design towards 2D Polymers: Synthesis of a Macrocycle with Three 1,8-Anthrylene Units

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