Solid-State Structure of Free Base Guanidine Achieved at Last

Takahiro Yamada; Xiaohui Liu; Ulli Englert; Hisanori Yamane; Richard Dronskowski

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Solid-State Structure of Free Base Guanidine Achieved at Last

机译：最后获得游离碱胍的固态结构

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Guanidine, (NH2)2C=NH, was first synthesized in 1861 by the oxidative degradation of an aromatic natural product, guanine, isolated from Peruvian guano.[1] Up to the present day, a multitude of scientific studies has been carried out on guanidine due to its peculiar chemical properties, for example, high basicity (pKA=13.6),[2] and also biological activity.[3] Moreover, guanidine is an important molecule in inorganic and organic synthesis, for example as a ligand in metal complexes,[4] but also as a molecular substructure for its many derivatives.[3, 5] Clearly, those species containing the guanidine moiety have attracted significant attention as electronically and sterically flexible ligands and functionally diverse biomolecules.

机译：胍盐（NH2）2C = NH，最早是从1469年从秘鲁鸟粪中分离出来的一种芳香族天然产物鸟嘌呤的氧化降解而合成的。[1]迄今为止，由于胍的独特的化学特性，例如高碱性（pKA = 13.6）[2]以及生物学活性[3]，已经对胍进行了大量科学研究。此外，胍是无机和有机合成中的重要分子，例如作为金属配合物中的配体，[4]也是其许多衍生物的分子亚结构。[3，5]显然，那些含有胍部分的物质具有电子和空间柔性配体和功能多样的生物分子引起了广泛的关注。

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《Chemistry: A European journal》 |2009年第23期|共5页
作者
Takahiro Yamada; Xiaohui Liu; Ulli Englert; Hisanori Yamane; Richard Dronskowski;
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正文语种 eng
中图分类应用化学;
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important molec; attracted significant; oxidative degradation;

机译：重要分子;吸引显着;氧化降解;

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1. Solid-State Structure of Free Base Guanidine Achieved at Last [J] . Takahiro Yamada, Xiaohui Liu, Ulli Englert, Chemistry: A European journal . 2009,第23期

机译：最后获得游离碱胍的固态结构
2. Solid-state structures of base-free lithium and sodium tetraphenylborates at room and low temperature: Comparison with the higher homologues MB(C _6H _5) _4 (M = K, Rb, Cs) [J] . Behrens U., Hoffmann F., Olbrich F. Organometallics . 2012,第3期

机译：室温和低温下无碱锂和四苯基硼酸钠的固态结构：与较高同系物MB（C _6H _5）_4（M = K，Rb，Cs）的比较
3. Solid-State Structures of Base-Free Rubidium and Cesium Pentamethylcyclopentadienides. Determination by High-Resolution Powder Diffraction [J] . Behrens U, Dinnebier RE, Neander S, Organometallics . 2008,第20期

机译：无碱Rub和五甲基环戊二烯化铯的固态结构。高分辨率粉末衍射法测定
4. Design of new block-copolymer systems to achieve thick-films with defect-free structures for applications of DSA into lithographic large nodes [C] . X. Chevalier, P. Coupillaud, G. Lombard, Advances in Patterning Materials and Processes XXXIII . 2016

机译：设计新的嵌段共聚物系统以实现具有无缺陷结构的厚膜，从而将DSA应用于光刻大节点
5. Applications of chiral guanidine organocatalysts in asymmetric transformations probing structure activity relationships of artificial enzyme active sites and development of metal-free oxidative cyclization reactions. [D] . Lovick, Helena M. 2009

机译：手性胍有机催化剂在不对称转化中的应用，探讨人工酶活性位点的结构活性关系和无金属氧化环化反应的发展。
6. A maskless synthesis of TiO2-nanofiber-based hierarchical structures for solid-state dye-sensitized solar cells with improved performance [O] . Dharani Sabba, Shweta Agarwala, Stevin S Pramana, 2014

机译：固态染料敏化太阳能电池的基于TiO2-纳米纤维的分层结构的无掩模合成
7. A chiral analog of the bicyclic guanidine TBD: synthesis, structure and Brønsted base catalysis [O] . Mariano Goldberg, Denis Sartakov, Jan W. Bats, 2016

机译：双环胍TBD的手性类似物：合成，结构和布朗斯台德碱催化

Solid-State Structure of Free Base Guanidine Achieved at Last

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