Synthesis and Reactivity of Functionalized Binary and Ternary Thiometallate Complexes [(RT)(4)S-6], [(RSn)(3)S-4](2-), [(RT)(2)(CuPPh3)(6)S-6], and [(RSn)(6)(OMe)(6)Cu2S6](4-) (R = C2H4COOH, CMe2CH2COMe; T = Ge, Sn)

Fard ZH; Xiong L; Muller C; Holynska M; Dehnen S

首页> 外文期刊>Chemistry: A European journal >Synthesis and Reactivity of Functionalized Binary and Ternary Thiometallate Complexes [(RT)(4)S-6], [(RSn)(3)S-4](2-), [(RT)(2)(CuPPh3)(6)S-6], and [(RSn)(6)(OMe)(6)Cu2S6](4-) (R = C2H4COOH, CMe2CH2COMe; T = Ge, Sn)

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Synthesis and Reactivity of Functionalized Binary and Ternary Thiometallate Complexes [(RT)(4)S-6], [(RSn)(3)S-4](2-), [(RT)(2)(CuPPh3)(6)S-6], and [(RSn)(6)(OMe)(6)Cu2S6](4-) (R = C2H4COOH, CMe2CH2COMe; T = Ge, Sn)

机译：官能化二元和三元硫代金属酸盐配合物[（RT）（4）S-6]，[（RSn）（3）S-4]（2-），[（RT）（2）（CuPPh3）（6）的合成和反应性）S-6]和[[RSn）（6）（OMe）（6）Cu2S6]（4-）（R = C2H4COOH，CMe2CH2COMe; T = Ge，Sn）

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A series of compounds comprising functionalized thiometallate cages [(RT)(4)S-6] (R terminated by COO(H) or COR groups), based on adamantane (T=Ge) or double-decker (T = Sn) type structures or [(RSn)(3)S-4](2-) anionic defect heterocubanes were synthesized and their reactions with 1) transition-metal compounds and 2) hydrazine derivatives were explored. Hence it was possible to generate functionalized ternary CuSnS or CuGeS Clusters and to transfer COR ligands into CR(N-NH2) or CR(N-NHPh) terminal groups, respectively. The report provides the proof-of-principle for a directed functionalization and derivatization of chalcogenidometallate cages with respect to the formation of chalcogeniclometallate-organic hybrid compounds containing M/E semiconductor nodes, as an alternative to the so far most prominent M/O combination in metal-organic frameworks. DFT investigations deliver further insight in the peculiarities of Ge/S versus Sn/S precursors and their products.

机译：基于金刚烷（T = Ge）或双层（T = Sn）类型的一系列化合物，包含官能化的硫金属酸盐笼[[RT]（4）S-6]（R终止于COO（H）或COR基团）合成结构或[（RSn）（3）S-4]（2-）阴离子缺陷杂合子，并研究它们与1）过渡金属化合物和2）肼衍生物的反应。因此，有可能产生功能化的三元CuSnS或CuGeS簇，并将COR配体分别转移到CR（N-NH2）或CR（N-NHPh）端基中。该报告提供了有关硫属元素金属化物笼子定向功能化和衍生化的原理证明，涉及形成含M / E半导体节点的硫属元素金属化物-有机杂化化合物，作为迄今为止最显着的M / O组合的替代方法。金属有机框架。 DFT研究提供了关于Ge / S与Sn / S前驱体及其产品的特殊性的进一步见解。

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《Chemistry: A European journal》 |2009年第27期|共10页
作者
Fard ZH; Xiong L; Muller C; Holynska M; Dehnen S;
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正文语种 eng
中图分类应用化学;
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chalcogens; cluster compounds; density functional calculations; germanium; structure elucidation; tin;

机译：硫族元素;团簇化合物;密度泛函计算;锗;结构解析;锡;

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1. Synthesis and Reactivity of Functionalized Binary and Ternary Thiometallate Complexes [(RT)(4)S-6], [(RSn)(3)S-4](2-), [(RT)(2)(CuPPh3)(6)S-6], and [(RSn)(6)(OMe)(6)Cu2S6](4-) (R = C2H4COOH, CMe2CH2COMe; T = Ge, Sn) [J] . Fard ZH, Xiong L, Muller C, Chemistry: A European journal . 2009,第27期

机译：官能化二元和三元硫代金属酸盐配合物[（RT）（4）S-6]，[（RSn）（3）S-4]（2-），[（RT）（2）（CuPPh3）（6）的合成和反应性）S-6]和[[RSn）（6）（OMe）（6）Cu2S6]（4-）（R = C2H4COOH，CMe2CH2COMe; T = Ge，Sn）
2. Rationally Functionalized Deltahedral Zintl Ions:Synthesis and Characterization of [Ge_9-ER_3]~(3-),[R_3E-Ge_9-ER_3]~(2-),and [R_3E-Ge_9-Ge_9-ER_3]~(4-)(E=Ge,Sn;R=Me,Ph) [J] . Angel ugrinov, Slavi C.Sevov Chemistry: A European journal . 2004,第15期

机译：合理功能化的三面体Zintl离子：[Ge_9-ER_3]〜（3-），[R_3E-Ge_9-ER_3]〜（2-）和[R_3E-Ge_9-Ge_9-ER_3]〜（4-）的合成与表征E = Ge，Sn; R = Me，Ph）
3. Design and Synthesis of Water-Soluble Multifunctionalizable Thiol-Reactive Polymeric Supports for Cellular Targeting [J] . Gok Ozgul, Kosif Irem, Dispinar Tugba, Bioconjugate Chemistry . 2015,第8期

机译：水溶性多官能团巯基反应性高分子靶向载体的设计与合成
4. Cover Picture: Synthesis and Reactivity of Functionalized Binary and Ternary Thiometallate Complexes (RT)4S6, (RSn)3S42−, (RT)2(CuPPh3)6S6, and (RSn)6(OMe)6Cu2S64−(R=C2H4COOH, CMe2CH2COMe; T=Ge, Sn) (Chem. Eur. J. 27/2009) [O] . Zohreh Hassanzadeh Fard, Lin Xiong, Christian Müller, 2009

机译：封面图片：官能化二元和三元硫胺络合物的合成和反应性复合物（RT）4S6，（RSN）3S4 2-，（RT）2（CupPH3）6S6，（RSN）6（OME）6Cu2S6 4-（r = C 2 H 4 COOH，CME2CH2; T = GE，SN）（CHEM。EUR。J. 27/2009）

Synthesis and Reactivity of Functionalized Binary and Ternary Thiometallate Complexes [(RT)(4)S-6], [(RSn)(3)S-4](2-), [(RT)(2)(CuPPh3)(6)S-6], and [(RSn)(6)(OMe)(6)Cu2S6](4-) (R = C2H4COOH, CMe2CH2COMe; T = Ge, Sn)

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