Ionic-Liquid-Supported (ILS) catalysts for asymmetric organic synthesis

Ni B.; Headley A.D.

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Ionic-Liquid-Supported (ILS) catalysts for asymmetric organic synthesis

机译：离子液体负载（ILS）催化剂用于不对称有机合成

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The asymmetric synthesis of compounds that contain new C-C and C-O bonds remains one of the most important types of synthesis in organic chemistry. Over the years, many different types of catalysts have been designed and used effectively to carry out such transformations. Ionic-liquid-supported (ILS) catalysts represent a new and very effective class of catalysts that are used to facilitate the asymmetric synthesis of such compounds. There are many advantages to using ILS catalysts; they are nontoxic, environmentally benign, and, most important, recyclable. An overview of the design, synthesis, mode of action, and effectiveness of this class of catalysts is reported.

机译：包含新的C-C和C-O键的化合物的不对称合成仍然是有机化学中最重要的合成类型之一。多年来，已经设计并有效地使用了许多不同类型的催化剂来进行这种转化。离子液体负载（ILS）催化剂代表了一种新型且非常有效的催化剂，可用于促进此类化合物的不对称合成。使用ILS催化剂有很多优点;它们无毒，对环境无害，而且最重要的是可回收。报告了这类催化剂的设计，合成，作用方式和有效性的概述。

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《Chemistry: A European journal》 |2010年第15期|共11页
作者
Ni B.; Headley A.D.;
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原文格式 PDF
正文语种 eng
中图分类应用化学;
关键词
Asymmetric synthesis; Homogeneous catalysis; Ionic liquids; Organocatalysis; Transition metals;

机译：不对称合成;均相催化;离子液体;有机催化;过渡金属;

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1. Ionic-Liquid-Supported (ILS) catalysts for asymmetric organic synthesis [J] . Ni B., Headley A.D. Chemistry: A European journal . 2010,第15期

机译：离子液体负载（ILS）催化剂用于不对称有机合成
2. Synthesis, characterization, and structures of oxovanadium(v) complexes of Schiff bases of beta-amino alcohols as tunable catalysts for the asymmetric oxidation of organic sulfides and asymmetric alkynylation of aldehydes [J] . Hsieh SH, Kuo YP, Gau HM Dalton transactions: An international journal of inorganic chemistry . 2007,第1期

机译：β-氨基醇席夫碱的Schov碱的氧钒（v）配合物的合成，表征和结构，作为可调节的有机硫化物不对称氧化和醛的不对称炔化催化剂
3. Direct and Post-Synthesis Incorporation of Chiral Metallosalen Catalysts into Metal-Organic Frameworks for Asymmetric Organic Transformations [J] . Xi Weiqin, Liu Yan, Xia Qingchun, Chemistry: A European journal . 2015,第36期

机译：直接和合成后的手性金属洛萨伦催化剂到金属有机骨架不对称有机转化的合并。
4. Asymmetric Amino Acid Synthesisby the Asymmetric Alkylation of Glycine Derivativeswith Chiral Spiro-Type and SimplifiedPhase-Transfer Catalysts [C] . Keiji Maruoka ACS symposium asymmetric synthesis and application of α-amino acids . 2009

机译：不对称氨基酸合成来自甘氨酸衍生物的不对称烷基化，With Chiral螺型和简化的晶态转移催化剂
5. Part I. Asymmetric organocatalysis: (1) Direct enantioselective organocatalytic hydroxymethylation of aldehydes catalyzed by alpha,alpha-diphenylprolinol trimethylsilyl ether: Application in the formal synthesis of (-)-Rasfonin; (2) Synthesis of a novel bicyclic secondary amine organocatalyst: Application to the direct enantioselective organocatalytic hydroxymethylation of aldehydes. Part II. Asymmetric synthesis of bicyclic analogues of the anti-osteoporotic drug risedronate. [D] . Miller, John Robert. 2010

机译：第一部分，不对称有机催化：（1）α，α-二苯基脯氨醇三甲基甲硅烷基醚催化的醛的直接对映选择性有机催化羟甲基化：在（-）-Rasfonin的正式合成中的应用；（2）新型双环仲胺有机催化剂的合成：应用于醛的直接对映选择性有机催化羟甲基化。第二部分抗骨质疏松药物Risedronate的双环类似物的不对称合成。
6. A Systematic Investigation of Quaternary Ammonium Ions as Asymmetric Phase Transfer Catalysts. Synthesis of Catalyst Libraries and Evaluation of Catalyst Activity [O] . Scott E. Denmark, Nathan D. Gould, Larry M. Wolf -1

机译：季铵离子的系统研究不对称相转移催化。催化剂库和催化剂活性评价的合成
7. Asymmetric Synthesis of Furan and Oxindole Derivatives with Bifunctional and Multifunctional Organic Catalysts [O] . DOU XIAOWEI 2013

机译：双功能和多功能有机催化剂不对称合成呋喃和羟吲哚衍生物

Ionic-Liquid-Supported (ILS) catalysts for asymmetric organic synthesis

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