β-protic pyrazole and N-heterocyclic carbene complexes: Synthesis, properties, and metal-ligand cooperative bifunctional catalysis

Kuwata S.; Ikariya T.

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β-protic pyrazole and N-heterocyclic carbene complexes: Synthesis, properties, and metal-ligand cooperative bifunctional catalysis

机译：β-质子吡唑和N-杂环卡宾配合物：合成，性质和金属-配体协同双功能催化

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This Minireview provides an overview of the chemistry of pyrazole and N-heterocyclic carbene (NHC) complexes bearing an NH group at the β-position to the metal. The synthesis and structures as well as the Br?nsted acidic nature of the β-NH group are described in detail. These complexes are attractive candidates for novel metal-ligand cooperative bifunctional catalysts, which would benefit highly effective molecular and energy transformations.

机译：本微型综述概述了在金属的β-位带有NH基团的吡唑和N-杂环卡宾（NHC）配合物的化学性质。详细介绍了β-NH基团的合成，结构以及布朗斯台德酸性。这些络合物是新型金属-配体协同双功能催化剂的有吸引力的候选物，它将有益于高效的分子和能量转化。

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《Chemistry: A European journal》 |2011年第13期|共15页
作者
Kuwata S.; Ikariya T.;
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正文语种 eng
中图分类应用化学;
关键词
carbene ligands; heterocyclic compounds; homogeneous catalysis; hydrogen bonds; organometallic compounds;

机译：卡宾配体;杂环化合物;均相催化;氢键;有机金属化合物;

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1. β-protic pyrazole and N-heterocyclic carbene complexes: Synthesis, properties, and metal-ligand cooperative bifunctional catalysis [J] . Kuwata S., Ikariya T. Chemistry: A European journal . 2011,第13期

机译：β-质子吡唑和N-杂环卡宾配合物：合成，性质和金属-配体协同双功能催化
2. Metal-ligand cooperative C-O bond cleavage of propargylic alcohol with protic pyrazole complexes of ruthenium [J] . Tashima Naoto, Ohta Satomi, Kuwata Shigeki Faraday discussions . 2019,第期

机译：金属配体与钌的质子吡唑复合物的丙吡咯醇合作C-O键切割
3. Central N-heterocyclic carbene moieties in protic pincer-type bis(pyrazole) ligands: Perturbation on steric and electronic properties of ruthenium center [J] . Toda Tatsuro, Kuwata Shigeki Journal of Organometallic Chemistry . 2020,第1期

机译：质子钳型BIS（吡唑）配体中的中央N-杂环切菜部分：钌中心的空间和电子性质的扰动
4. Pincer and Chelate N-Heterocyclic Carbene Complexes of Rh, Ir, and Pd: Synthetic Routes, Dynamics, Catalysis, Abnormal Binding, and Counterion Effects [C] . Anthony R. Chianese, Robert H. Crabtree, American Chemical Society(ACS, American Chemical Society National Meeting . 2004

机译：RH，IR和PD的钳子和螯合物N-杂环Carbene络合物：合成路线，动力学，催化，异常绑定和反压缩效应
5. Organometallic complexes of tris(oxazolinyl)borate and mixed N-heterocyclic carbene-oxazolinylborate: Synthesis and catalysis. [D] . Xu, Songchen. 2015

机译：三（恶唑啉基）硼酸盐和N-杂环卡宾-恶唑啉基硼酸盐混合的有机金属配合物：合成和催化。
6. N-Heterocyclic carbene/Brønsted acid cooperative catalysis as a powerful tool in organic synthesis [O] . Rob De Vreese, Matthias D’hooghe 2012

机译：N-杂环卡宾/布朗斯台德酸协同催化作为有机合成的有力工具
7. Versatile relay and cooperative palladium(0) N-heterocyclic carbene/copper(I) N-heterocyclic carbene catalysis for the synthesis of tri- and tetrasubstituted alkenes [O] . Lesieur, Mathieu, Bidal, Yannick Daniel, Lazreg, Faima, 2015

机译：多功能中继和协作钯（0）N-杂环卡宾/铜（I）N-杂环卡宾催化合成三和四取代烯烃

β-protic pyrazole and N-heterocyclic carbene complexes: Synthesis, properties, and metal-ligand cooperative bifunctional catalysis

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