• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Polymer: The International Journal for the Science and Technology of Polymers >Reinforcement of model filled elastomers: characterization of the cross-linking density at the filler-elastomer interface by ~1H NMR measurements
【24h】

Reinforcement of model filled elastomers: characterization of the cross-linking density at the filler-elastomer interface by ~1H NMR measurements

机译：模型填充弹性体的增强：通过〜1H NMR测量表征填充剂-弹性体界面处的交联密度

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

The cross-linking density at the filler-elastomer interface is analyzed by ~1H NMR measurements in model reinforced elastomers composed by grafted nanosilica particles and corss-linked ethylacrylate chains. We have focused our attention on the effect of introducing fillers on the relaxation of the bulk polymer matrix which is observed at long times (t > 100 mus), Measurements performed at high temperature (T > T_g + 120 K) have revealed that its relaxation is affected by the topological constraints existing at the particle surface. We deduce that the effect of particles in the bulk matrix can be interpreted as that of an homogeneous additional constraint density which increases proportionally to the surface area introduced in the matrix.
机译：填料-弹性体界面处的交联密度通过1 H NMR测量在由接枝的纳米二氧化硅颗粒和皮质连接的丙烯酸乙酯链组成的模型增强弹性​​体中进行分析。我们将注意力集中在引入填料对长时间（t> 100 mus）观察到的本体聚合物基体弛豫的影响上。在高温（T> T_g + 120 K）下进行的测量表明，其弛豫受粒子表面存在的拓扑约束的影响。我们推论，整体基质中颗粒的影响可以解释为均匀的附加约束密度的影响，该密度随引入基质中的表面积成比例增加。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号