A Direct Link between Annulene and Porphyrin Chemistry-21-Vacataporphyrin

Ewa Pacholska; Lechoslaw Latos-Grazynski; Zbigniew Ciunik

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A Direct Link between Annulene and Porphyrin Chemistry-21-Vacataporphyrin

机译：Annulene和卟啉化学21-Vacataporphyrin之间的直接联系

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A novel molecule, aza-deficient porphyrin 5,10-15,20-tetraaryl-21-vacataporphyrin has been synthesised by a substraction of a tellurium atom from 5,10-15,20-tetraaryl-21-telluraporphyrin under treatment of HCl. The new macrocycle is an annulene-porphyrin hybrid and at the same time is directly related to 21-heteroporphyrins but has a vacant space instead of heteroatomic bridge. The molecule preserves the fundamental structural and spectroscopic features of the parental 5,10-15,20-tetraarylporphyrin with three nitrogen atoms and two CH groups favorably prearranged for coordination.

机译：通过在盐酸处理下从5,10-15,20-四芳基-21-碲卟啉中减去碲原子，合成了一种新的氮杂缺陷型卟啉5,10-15,20-四芳基-21-vacataporphyrin。新的大环是年轮虫-卟啉的杂种，同时与21-杂卟啉有直接关系，但具有空位而不是杂原子桥。该分子保留了亲本的5,10-15,20-四芳基卟啉的基本结构和光谱特征，其中三个氮原子和两个CH基团有利地预先安排用于配位。

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来源
《Chemistry: A European journal》 |2002年第23期|共4页
作者
Ewa Pacholska; Lechoslaw Latos-Grazynski; Zbigniew Ciunik;
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正文语种 eng
中图分类化学;应用化学;
关键词
annulenes; porphyrinoids; tellurium;

机译：环;卟啉类;碲;

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1. A Direct Link between Annulene and Porphyrin Chemistry-21-Vacataporphyrin [J] . Ewa Pacholska, Lechoslaw Latos-Grazynski, Zbigniew Ciunik Chemistry: A European journal . 2002,第23期

机译：Annulene和卟啉化学21-Vacataporphyrin之间的直接联系
2. Macrocyclic [4n+2]-Huckel aromatic systems up to n = 9 and [4n] antiaromatic systems up to n = 10: Homologous sequences from tetraepoxy[24]annulene(2.0.2.0) to tetraepoxy[40]annulene(12.0.12.0) and from the 'tetraoxa[22]porphyrin(2.0.2.0)'- to the 't [J] . Markl V., Kreitmeier P., Burgemeister T., Helvetica chimica acta . 1998,第8期

机译：高达n = 9的大环[4n + 2] -Huckel芳族体系和高达n = 10的[4n]抗芳族体系：从四环氧[24]环戊烯（2.0.2.0）到四环氧[40]环戊烯（12.0.12.0）的同源序列）和从'tetraoxa [22] porphyrin（2.0.2.0）'-到't
3. Porphyrin “Lego Block” Strategy To Construct Directly meso–β Doubly Linked Porphyrin Rings† [J] . Jianxin Song Dr., Naoki Aratani Dr., Pyosang Kim, Angewandte Chemie . 2010,第21期

机译：卟啉“乐高阻滞”策略直接构建内消旋-β双连接的卟啉环†
4. Resonance Raman Spectra of Directly-Linked Linear Porphyrin Arrays up to 128 Porphyrin Units [C] . D. H. Jeong International conference on Raman spectroscopy;ICORS 2000 . 2000

机译：直接连接的线性卟啉阵列的共振拉曼光谱，最高可达128个卟啉单元
5. Electrochemical and spectroelectrochemical studies: From building blocks of porphyrins to extended porphyrin-like molecule linkages. [D] . Zhang, Min. 2008

机译：电化学和光谱电化学研究：从卟啉的组成部分到扩展的卟啉样分子连接。
6. Synthesis and spectroscopic properties of β-meso directly linked porphyrin–corrole hybrid compounds [O] . Baris Temelli, Hilal Kalkan 2018

机译：β-内消旋直接连接的卟啉-Corrole杂化化合物的合成及光谱性质
7. Porphyrin Synthesis in Water Provides New Expanded Porphyrins with Direct Bipyrrole Linkages: Isolation and Characterization of Two Heptaphyrins [O] . -1

机译：水中的卟啉合成提供了具有直接双吡咯键的新的膨胀卟啉：两种七吡喃的分离和表征

A Direct Link between Annulene and Porphyrin Chemistry-21-Vacataporphyrin

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