An oxidative prins-pinacol tandem process and its application to the synthesis of (-)-platensimycin

Beaulieu M.-A.; Sabot C.; Achache N.; Guérard K.C.; Canesi S.

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An oxidative prins-pinacol tandem process and its application to the synthesis of (-)-platensimycin

机译：prins-频哪醇串联氧化工艺及其在合成（-）-platensimycin中的应用

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Center stage: An oxidative Prins-pinacol tandem process mediated by a hypervalent iodine reagent has been accomplished. The strategy allows rapid access to highly functionalized spirocyclic cores (see scheme) present in many natural products. A first application to the formal synthesis of (?)-platensimycin has been achieved.

机译：中心阶段：已经完成了由高价碘试剂介导的氧化Prins-频哪醇串联过程。该策略允许快速访问许多天然产品中存在的高度官能化的螺环核（请参阅方案）。已经实现了正式合成（β）-平台霉素的首次应用。

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《Chemistry: A European journal》 |2010年第37期|共5页
作者
Beaulieu M.-A.; Sabot C.; Achache N.; Guérard K.C.; Canesi S.;
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正文语种 eng
中图分类应用化学;
关键词
Hypervalent compounds; Iodine; Natural products; Oxidation; Prins-pinacol reaction; Umpolung;

机译：高价化合物;碘;天然产物;氧化;Prins-频哪醇反应;Umpolung;

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1. An oxidative prins-pinacol tandem process and its application to the synthesis of (-)-platensimycin [J] . Beaulieu M.-A., Sabot C., Achache N., Chemistry: A European journal . 2010,第37期

机译：prins-频哪醇串联氧化工艺及其在合成（-）-platensimycin中的应用
2. An Oxidative Prins–Pinacol Tandem Process and its Application to the synthesis of (−)-Platensimycin [J] . Marc-Andreacute, Beaulieu Dr. Cyrille Sabot Nabil Achache Kimiaka C. Gueacute, rard Prof. Dr. Sylvain Canesi Chemistry - A European Journal . 2010,第37期

机译：Prins-Pinacol串联氧化过程及其在（-）-Platensimycin合成中的应用
3. Oxidative prins-pinacol tandem process mediated by a hypervalent iodine reagent: Scope, limitations, and applications [J] . Beaulieu M.-A., Guérard K.C., Maertens G., The Journal of Organic Chemistry . 2011,第22期

机译：高价碘试剂介导的氧化普林-频哪醇串联过程：范围，局限性和应用
4. DESIGN AND FABRICATION OF HIGHLY ENVIRONMENTAL STABLE Cr-Fe-Ni oxides/ ZrO_2-SiO_2 COMPOSITE OXIDE BASED TANDEM ABSORBER FOR SOLAR THERMAL POWER GENERATION APPLICATIONS [C] . T. Vijayaraghavan, M. Shiva Prasad, S. Sakthivel, ISES solar world congress . 2015

机译：太阳能热发电应用的高环境稳定Cr-Fe-Ni氧化物/ ZrO_2-SiO_2复合氧化物串联式吸尘器的设计与制造
5. I. The tandem chain extension-acylation reaction. II. Synthesis of papyracillic acid A: Application of the tandem homologation-acylation reaction. III. Synthesis of tetrahydrofuran-based peptidomimetics. [D] . Spencer, Carley Meredith. 2013

机译：I.串联链延伸-酰化反应。二。纸莎草酸A的合成：串联同源化-酰化反应的应用。三，合成基于四氢呋喃的拟肽。
6. Enzymatic Processing of Fumiquinazoline F: A Tandem Oxidative-Acylation Strategy for the Generation of Multicyclic Scaffolds in Fungal Indole Alkaloid Biosynthesis [O] . Brian D. Ames, Xinyu Liu, Christopher T. Walsh -1

机译：的Fumiquinazoline F酶促处理：串联式氧化酰化策略多环支架的在真菌吲哚生物碱生物合成的代
7. Cryptic and Stereospecific Hydroxylation, Oxidation, and Reduction in Platensimycin and Platencin Biosynthesis [O] . Liao-Bin Dong, Xiao Zhang, Jeffrey D. Rudolf, 2019

机译：Plyctic和立体特异性羟基化，氧化和降低铂霉素和Platencin生物合成

An oxidative prins-pinacol tandem process and its application to the synthesis of (-)-platensimycin

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