MORPHOLOGY OF MICROPOROUS POLYMERIC MATERIALS BY POLYMERIZATION OF METHYL METHACRYLATE AND 2-HYDROXYETHYL METHACRYLATE IN MICROEMULSIONS

Chieng TH.; Chew CH.; Ng SC.; Gan LM.

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MORPHOLOGY OF MICROPOROUS POLYMERIC MATERIALS BY POLYMERIZATION OF METHYL METHACRYLATE AND 2-HYDROXYETHYL METHACRYLATE IN MICROEMULSIONS

机译：甲基丙烯酸甲酯和2-羟甲基丙烯酸甲酯在微乳液中聚合形成微孔聚合物的形态

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A microemulsion system consisting of methyl methacrylate (MMA), 2-hydroxyethyl methacrylate (HEMA) and a crosslinking agent, ethylene glycol dimethacrylate, in water using sodium dodecyl sulfate as a surface-active agent was investigated. A study on the phase behaviour of the system was conducted to determine the type of microstructures that may be present. Polymerization was carried out at room temperature using dibenzyl ketone as a photoinitiator. The morphology (microstructure) of the resulting polymeric materials was found to depend strongly on the composition (water content, surfactant content, and MMA to HEMA ratio) of the precursor microemulsions. [References: 24]

机译：使用十二烷基硫酸钠作为表面活性剂，研究了一种由甲基丙烯酸甲酯（MMA），甲基丙烯酸2-羟乙酯（HEMA）和交联剂乙二醇二甲基丙烯酸酯组成的微乳液体系。对系统的相行为进行了研究，以确定可能存在的微结构的类型。使用二苄基酮作为光引发剂在室温下进行聚合。发现所得聚合物材料的形态（微观结构）在很大程度上取决于前体微乳液的组成（水含量，表面活性剂含量以及MMA与HEMA之比）。 [参考：24]

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《Polymer: The International Journal for the Science and Technology of Polymers》 |1995年第10期|共6页
作者
Chieng TH.; Chew CH.; Ng SC.; Gan LM.;
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正文语种 eng
中图分类高分子化学（高聚物）;高分子化合物工业（高聚物工业）;
关键词
Microporous polymers; Morphology; Microemulsion polymerization; Scattering; Systems;

机译：微孔聚合物;形貌;微乳液聚合;散射;体系;

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1. Morphology of thermally polymerized microporous polymer materials prepared from methyl methacrylate and 2-hydroxyethyl methacrylate microemulsions [J] . Schmuhl N., Cheung HM., Davis E. Langmuir: The ACS Journal of Surfaces and Colloids . 1998,第4期

机译：由甲基丙烯酸甲酯和甲基丙烯酸2-羟乙酯微乳液制备的热聚合微孔聚合物材料的形貌
2. MORPHOLOGY OF MICROPOROUS POLYMERIC MATERIALS BY POLYMERIZATION OF METHYL METHACRYLATE AND 2-HYDROXYETHYL METHACRYLATE IN MICROEMULSIONS [J] . Chieng TH., Chew CH., Ng SC., Polymer: The International Journal for the Science and Technology of Polymers . 1995,第10期

机译：甲基丙烯酸甲酯和2-羟甲基丙烯酸甲酯在微乳液中聚合形成微孔聚合物的形态
3. FORMATION OF MICROPOROUS POLYMERIC MATERIALS BY MICROEMULSION POLYMERIZATION OF METHYL METHACRYLATE AND 2-HYDROXYETHYL METHACRYLATE [J] . Chieng TH., Chew CH., Ng SC., Journal of Applied Polymer Science . 1996,第10期

机译：甲基丙烯酸甲酯和2-羟甲基丙烯酸甲酯的微乳液聚合形成微孔聚合物
4. A comparison of the Deformation and Fracture Mechanisms in Rubber Toughened Poly(methyl methacrylate) and in Poly(urethane) / Poly(methyl methacrylate) Interpenetrating Polymer Networks [C] . Ph. BEGUELIN Advances in Mechanical Behaviour, Plasticity and Damage: Proceedings of EUROMAT 2000 . 2000

机译：橡胶增韧聚甲基丙烯酸甲酯和聚氨酯/聚甲基丙烯酸甲酯互穿聚合物网络中变形和断裂机理的比较
5. Vibrational overtone spectroscopy of several mono- and polyacrylates, azo-initiators and polysiloxanes, vibrationally initiated polymerization of methyl methacrylate and methyl methacrylate-polysiloxane mixtures. [D] . Gerasimov, Timofey G. 2002

机译：几种单丙烯酸和聚丙烯酸酯，偶氮引发剂和聚硅氧烷的振动泛音谱，甲基丙烯酸甲酯和甲基丙烯酸甲酯-聚硅氧烷混合物的振动引发聚合。
6. Synthesis of Poly(2-Acrylamido-2-Methylpropane Sulfonic Acid) and its Block Copolymers with Methyl Methacrylate and 2-Hydroxyethyl Methacrylate by Quasiliving Radical Polymerization Catalyzed by a Cyclometalated Ruthenium(II) Complex [O] . Vanessa Martínez-Cornejo, Joaquin Velázquez-Roblero, Veronica Rosiles-González, 2020

机译：通过环状钌（II）复合物催化的Quasiliving自由基聚合用甲基丙烯酸甲酯和甲基丙烯酸甲酯的甲基丙烯酸甲酯和2-羟乙基甲基丙烯酸甲酯的合成
7. Scientific Opinion on the safety evaluation of the active substances, terephthalic acid, dimethyl ester , polymer with 1,4-butanediol, cyclized, polymers with glycidyl methacrylate, hydroxyl-terminated polybutadiene, methyl methacrylate and styrene, and cobalt stearate for use in food contact materials [O] . EFSA Panel on Food Contact Materials, Enzymes, Flavourings and Processing Aids (CEF) 2012

机译：关于对食品接触中使用的活性物质，对苯二甲酸，二甲酯，与1,4-丁二醇的聚合物，环化，与甲基丙烯酸缩水甘油酯的聚合物，羟基封端的聚丁二烯，甲基丙烯酸甲酯和苯乙烯以及硬脂酸钴的安全性评估的科学意见材料
8. Characterization by Tin-Specific Size Exclusion Chromatography of the Free Radical Copolymerization of Tributyltin Methacrylate and Methyl Methacrylate [R] . Parks, E. J., Brinckman, F. E., Mullin, C. E., 1980

机译：锡特异性尺寸排阻色谱法表征甲基丙烯酸三丁酯与甲基丙烯酸甲酯的自由基共聚

MORPHOLOGY OF MICROPOROUS POLYMERIC MATERIALS BY POLYMERIZATION OF METHYL METHACRYLATE AND 2-HYDROXYETHYL METHACRYLATE IN MICROEMULSIONS

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