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首页> 外文期刊>Chemistry: A European journal >Comparative analyses of a family of potential self-replicators: The subtle interplay between molecular structure and the efficacy of self-replication
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Comparative analyses of a family of potential self-replicators: The subtle interplay between molecular structure and the efficacy of self-replication

机译：一系列潜在自我复制者的比较分析：分子结构与自我复制功效之间的微妙相互作用

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摘要

It is envisioned that protocols based on self-replication will emerge as a formidable synthetic apparatus for the production of nanoscale assemblies through molecular structures that are capable of automultiplication with high reaction rates and selectivities. To achieve this goal, a complete understanding of the relationship between molecular structure and replication efficiency is necessary. Rigorous experimental and theoretical analyses of a series of self-complementary scaffolds that are intimately related in a constitutional sense, manufactured through the Diels-Alder reaction of complementary subunits, were undertaken. Experimental and computational methods were employed to map the key determinants that dictate the emergence of self-replicative function, as well as the efficiency, rate and selectivity of the self-replicative processes.
机译：可以预见，基于自我复制的协议将作为一种强大的合成设备出现，该设备通过分子结构能够以高反应速率和选择性进行自动复制，从而生产纳米级组件。为了实现这一目标，必须全面了解分子结构和复制效率之间的关系。进行了严格的实验和理论分析，这些研究是通过互补亚基的Diels-Alder反应制得的，在结构意义上密切相关的一系列自我互补支架。实验和计算方法被用来映射决定自我复制功能的出现的关键因素，以及自我复制过程的效率，速率和选择性。

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