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Programmed Construction of Discrete Self-Assembled Cyclic Aggregates

机译:离散自组装循环骨料的程序化构建

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摘要

Examples for programmed self-assembly of #alpha#, #beta#-undaturated ketoximes carrying a terminal pyridine subunit are described. The solid-state structures of a series of pyridinyl #alpha#,#beta#-unsaturated ketoximes 1 were investigated by X-ray structural analysis; this demonstrated that molecules 3-5 predictably form discrete cyclic aggregates stabilized by a network of hydrogen bonds and aromatic interactions.
机译:描述了带有末端吡啶亚基的#alpha#,#beta#-不饱和酮肟的程序化自组装的实例。通过X射线结构分析研究了一系列吡啶基#α#,#β#-不饱和酮肟的固态结构。这表明分子3-5可预测地形成离散的环状聚集体,并通过氢键和芳族相互作用的网络稳定化。

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