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Eutectic-Based Ionic Liquids with Metal-Containing Anions and Cations

机译:含金属阴离子和阳离子的基于共晶的离子液体

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摘要

Eutectic mixtures of zinc chloride and donor molecules such as urea and acetamide are described and it is proposed that these constitute a new class of ionic liquids.FAB-MS analysis shows that the liquids are made up of metal-containing anions and cations in which the donor is coordinated to the cation.Data on the viscosity,conductivity,density,phase behaviour and surface tension are presented and these are shown to be significantly different to other related ionic liquids that incorporate quaternary ammonium salts.The conductivity and viscosity are comparable with other ionic liquids and the data fit well to the Hole theory model recently proposed.
机译:描述了氯化锌与施主分子(如尿素和乙酰胺)的共晶混合物,并建议将它们构成一类新型的离子液体。FAB-MS分析表明,该液体由含金属的阴离子和阳离子组成,其中供体与阳离子配合使用。给出了有关粘度,电导率,密度,相行为和表面张力的数据,这些数据与掺有季铵盐的其他相关离子液体显着不同。电导率和粘度与其他离子液体相当离子液体和数据非常适合最近提出的霍尔理论模型。

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