Intramolecular Allyl Transfer Reaction from Allyl Ether to Aldehyde Groups: Experimental and Theoretical Studies

Delpohine Franco; Karin Wenger; Serge Antonczak; Cabrol-Bass; Elishbet Dunach; Mece Rocamora; Montserrat Gomez; Guillermo mullr

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Intramolecular Allyl Transfer Reaction from Allyl Ether to Aldehyde Groups: Experimental and Theoretical Studies

机译：从烯丙基醚到醛基的分子内烯丙基转移反应：实验和理论研究

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The intramolecular transfer of the allyl group of functionalized allyl aryl ethers to an aldehyde group in the presence of Ni~o complexes was studied from chemical , electrochemical and theoretical point of view. The chemical reacion involves the addition of Ni~o to the allyl ether followed by stoichiometic allylation. The electrochemical process is catalytic in nickel and involves the reduction of intermidiate #eta#-allylnickeL(II) complexes

机译：从化学，电化学和理论的角度研究了在Ni-o配合物存在下官能化的烯丙基芳基醚的烯丙基向醛基的分子内转移。化学反应包括向烯丙基醚中添加Ni〜o，然后进行化学计量的烯丙基化。电化学过程在镍中具有催化作用，并且涉及中间体＃eta＃-alallynickeL（II）配合物的还原

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来源
《Chemistry: A European journal》 |2002年第3期|共9页
作者
Delpohine Franco; Karin Wenger; Serge Antonczak; Cabrol-Bass; Elishbet Dunach; Mece Rocamora; Montserrat Gomez; Guillermo mullr;
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正文语种 eng
中图分类化学;应用化学;
关键词
allylation; electrochemistry; homogeneous catalysis; nickel;

机译：烯丙基化;电化学;均相催化;镍;

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1. Intramolecular Allyl Transfer Reaction from Allyl Ether to Aldehyde Groups: Experimental and Theoretical Studies [J] . Delpohine Franco, Karin Wenger, Serge Antonczak, Chemistry: A European journal . 2002,第3期

机译：从烯丙基醚到醛基的分子内烯丙基转移反应：实验和理论研究
2. Stereoselective 4-benzyloxybut-2-enylation of aldehydes via an allyl-transfer reaction using a chiral allyl donor [J] . Shafi SM, Chou J, Kataoka K, Organic letters . 2005,第14期

机译：醛通过手性烯丙基供体的烯丙基转移反应进行立体选择性4-苄氧基丁-2-烯基化
3. Stereoselective 4-benzyloxybut-2-enylation of aldehydes via an allyl-transfer reaction using a chiral allyl donor [J] . Shafi SM, Chou J, Kataoka K, Organic letters . 2005,第14期

机译：醛通过手性烯丙基供体的烯丙基转移反应进行立体选择性的4-苄氧基丁-2-烯化
4. Ru/CeO2-Catalyzed Allyl Transfer Reaction of Homoallyl Alcohols to Aldehydes via C-C Bond Cleavage [C] . Hiroki Miura, Saburo Hosokawa, Teruyuki Kondo Symposium on Organometallic Chemistry . 2008

机译：Ru / CeO 2催化通过C-C键切割将Homoall醇的烯丙基转移反应转化为醛
5. Kinetics Studies of Two Free Radicals, Amidogen Radical and Allyl Radical: Amidogen Radical(A2A1) Emission Lifetimes in the (0,9,0) and (0,8,0) Bands and Allyl Radical Reactions With Nitrogen Dioxide, Methyl Radical and Allyl Radical. [D] . N'Doumi, Marc. 2012

机译：两种自由基的动力学研究：酰胺基自由基和烯丙基自由基：（0,9,0）和（0,8,0）谱带中的酰胺基自由基（A2A1）发射寿命以及二氧化氮，甲基自由基和烯丙基的烯丙基自由基反应基。
6. Gas-Phase Pyrolytic Reaction of 4-Aryl-3-buten-2-ols and Allyl Benzyl Ethers: Kinetic and Mechanistic Study [O] . Alya M. Al-Etaibi, Nouria A. Al-Awadi, Maher R. Ibrahim, 2010

机译：4-芳基-3-丁烯-2-醇与烯丙基苄醚的气相热解反应：动力学和机理研究
7. Stereoselective 4-Benzyloxybut-2- enylation of Aldehydes via an Allyl- Transfer Reaction Using a Chiral Allyl Donor [O] . -1

机译：使用手性烯丙基供体，通过烯丙基转移反应的立体选择4-苄氧基抑制-2-醛化合物
8. Theoretical and experimental study of unimolecular and biomolecular radical hydrogen transfer reactions. [R] . J. A. Franz T. Autrey G. J. Gleicher D. Camaioni K. F. Ferris 1991

机译：单分子和生物分子自由基氢转移反应的理论和实验研究。

Intramolecular Allyl Transfer Reaction from Allyl Ether to Aldehyde Groups: Experimental and Theoretical Studies

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