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Structure characterization and possible bioggenesis of three new families of nortriterpenoids: Schisanartane, schiartane, and 18-norschiartane

机译:三种新的降冰片萜类家族的结构表征和可能的生物发生机理:五味子烷,七烷烷和18-正七烷烷

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摘要

Four new, highly oxygenated nortriterpenoids with unique schisanartane skeletons, micrandilactones D-G (1-4), have been isolated from the leaves and stems of Schisandra micrantha, and their structures have been elucidated on the basis of extensive spectral studies. The postulated biogenetic sequences of sixteen highly oxygenated nortriterpenoids and bisnortriterpenoids with new skeletons from three Schisandra species are discussed and have been compared from a chemotaxonomic standpoint.
机译:从五味子的五味子的茎和叶中分离出四种具有独特的五味子烷骨架的新的高度氧化的去甲类异戊二烯类化合物micrandilactones D-G(1-4),并在广泛的光谱研究基础上阐明了它们的结构。从化学分类学的角度,对假定的十六种高度氧化的去甲三萜和双去甲三萜具有新骨架的生物遗传序列进行了讨论,并进行了比较。

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