Preparation and Redox Properties of N,N,N-l,3,5-Trialkylated Flavin Derivatives and Their Activity as Redox Catalysts

Auri A.Linen; Nina Hermanns; Sascha Ott; Lars Kruger

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Preparation and Redox Properties of N,N,N-l,3,5-Trialkylated Flavin Derivatives and Their Activity as Redox Catalysts

机译：N，N，N-1，3，5-三烷基黄素衍生物的制备，氧化还原性能及其氧化还原活性

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Eight different flavin derivatives have been synthesized and the electronic effects of substituents in various positions on the flavin redox chemistry were investigated.The redox potentials of the flavins,determined by cyclic voltam-metry,correlated with their efficiency as catalysts in the H_2O_2 oxidation of methyl p-tolyl sulfide.Introduction of electron-withdrawing groups increased the stability of the reduced catalyst precursor.

机译：合成了八种不同的黄素衍生物，研究了不同位置的取代基对黄素氧化还原化学反应的电子效应。用循环伏安法测定了黄素的氧化还原电位，与它们作为甲基的H_2O_2氧化催化剂的效率有关。对甲苯基硫化物。吸电子基团的引入增加了还原的催化剂前体的稳定性。

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《Chemistry: A European journal》 |2005年第1期|共8页
作者
Auri A.Linen; Nina Hermanns; Sascha Ott; Lars Kruger;
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正文语种 eng
中图分类化学;
关键词
cyclic voltammetry flavins; redox catalysis; redox chemistry;

机译：循环伏安法黄素;氧化还原催化;氧化还原化学;

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1. Preparation and Redox Properties of N,N,N-l,3,5-Trialkylated Flavin Derivatives and Their Activity as Redox Catalysts [J] . Auri A.Linen, Nina Hermanns, Sascha Ott, Chemistry: A European journal . 2005,第1期

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Preparation and Redox Properties of N,N,N-l,3,5-Trialkylated Flavin Derivatives and Their Activity as Redox Catalysts

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