Cooperative recognition of C-60-ammonium substrates by a ditopic oligophenylenevinylene/crown ether host

Elhabiri M; Trabolsi A; Cardinali F; Hahn U; Albrecht-Gary AM; Nierengarten JF

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Cooperative recognition of C-60-ammonium substrates by a ditopic oligophenylenevinylene/crown ether host

机译：异位低聚亚苯基亚乙烯基/冠醚主体对C-60铵底物的协同识别

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A new fullerene derivative with an ammonium subunit has been prepared. Its ability to form supramolecular complexes with oligophenylenevinylene derivatives bearing one or two crown ether moieties has been evidenced by electrospray mass spectrometry, and UV-visible and luminescence spectroscopy experiments. Interestingly, the assembly of the C-60-ammonium cation with the oligophenylenevinylene derivative bearing two crown ether moieties leads to the cooperative formation of the 2:1 complex owing to intramolecular fullerene-fullerene interactions.

机译：已经制备了具有铵亚基的新的富勒烯衍生物。通过电喷雾质谱，UV-可见光和发光光谱实验证明了其与带有一个或两个冠醚部分的低聚亚苯基亚乙烯基衍生物形成超分子络合物的能力。有趣的是，由于分子内富勒烯-富勒烯相互作用，C-60-铵阳离子与带有两个冠醚部分的低聚亚苯基亚乙烯基衍生物的组装导致2：1配合物的协同形成。

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《Chemistry: A European journal》 |2005年第16期|共6页
作者
Elhabiri M; Trabolsi A; Cardinali F; Hahn U; Albrecht-Gary AM; Nierengarten JF;
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正文语种 eng
中图分类化学;
关键词
cooperative phenomena; crown compounds; fullerenes; pi-conjugated system; supramolecular chemistry; MULTIWAVELENGTH SPECTROSCOPIC DATA; EQUILIBRIUM-CONSTANTS; PHOTOVOLTAIC DEVICES; PHOTOINDUCED ENERGY; CHARGE-TRANSFER; PORPHYRIN DYAD; SOLAR-CELLS; DERIVATIVES; CONJUGATE; COMPLEXATION;

机译：合作现象;冠状化合物;富勒烯;π-共轭体系;超分子化学;多波长光谱数据;平衡常数;光电子器件;光诱导的能量;电荷转移;卟啉染料;太阳能电池;硅藻土;

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1. Cooperative recognition of C-60-ammonium substrates by a ditopic oligophenylenevinylene/crown ether host [J] . Elhabiri M, Trabolsi A, Cardinali F, Chemistry: A European journal . 2005,第16期

机译：异位低聚亚苯基亚乙烯基/冠醚主体对C-60铵底物的协同识别
2. Organotin‐Functionalized Crown Ethers as Ditopic Hosts for Lithium Salts: Synthesis, Structures and Complexation Studies of X ₃3 SnCH ₂2 [16]‐crown‐5 (X = I, Br, Cl) [J] . Arens Verena, Naseer Muhammad Moazzam, Lutter Michael, European journal of inorganic chemistry . 2018,第13期

机译：有机辛官能化冠醚作为锂盐的多透载体：X _{3 3 snch _{2 2 [16] -crown-5（x = i）的合成，结构和络合研究。-5（x = i ，z，cl）}}
3. Synthesis of Fullerodendrons with an Ammonium Unit at the Focal Point and Their Cooperative Self-Assembly on a Fluorescent Ditopic Crown Ether Receptor [J] . Jean-Francois Nierengarten, Uwe Hahn, All Trabolsi, Chemistry: A European journal . 2006,第12期

机译：在焦点处具有铵单元的富勒烯的合成及其在荧光异位冠醚受体上的协同自组装
4. Desorption Electrospray Ionization Reactions Between Host Crown Ethers and the Influenza Neuraminidase Inhibitor Oseltamivir for the Screening of Potentially Counterfeit Tamiflu~(~R). [C] . Leonard Nyadong, Edward G. Hohenstein, Kristin Johnson, ASMS Conference on Mass Spectrometry and Allied Topics . 2008

机译：解吸电喷雾电离反应宿主醚和流感神经氨酸酶抑制剂Oseltamivir用于筛选潜在的伪造塔米......（〜r）。
5. Host-guest systems based on crown ether, cryptand, and pseudocryptand hosts with paraquat, diquat, secondary ammonium, and monopyridinium salt guests. [D] . Huang, Feihe. 2005

机译：基于冠状醚，穴状和假穴状的宿主-来宾系统，具有百草枯，敌草快，仲铵和一吡啶鎓盐来宾。
6. Supramolecular Polymers With AIE Property Fabricated From a Cyanostilbene Motif-Derived Ditopic Benzo-21-Crown-7 and a Ditopic Dialkylammonium Salt [O] . Haoran Wu, Tangxin Xiao 2020

机译：具有由氰蛋白酶衍生的DITopic苯并-21-冠-7制造的AIE属性的超分子聚合物和DITopic二烷基铵盐
7. Electrochemical and19F NMR Detection of Anions, Ion-pairs, and a Zwitterionic Amino Acid with a Ferrocene-based Hetero-ditopic Receptor Bearing o-(Carboxamido)trifluoroacetophenone and Crown-ether Ligands [O] . 2008

机译：用亚茂铁基杂核受体轴承O-（Carboxamino）三氟乙酮和冠状醚配体的电化学和19F NMR检测轴承率，离子对和两性离子氨基酸检测
8. From Liquid Crystal Polymers Containing Crown Ethers to Tapered Building BlocksContaining Crown Ethers Which Self-Assemble into Tubular Supermolecules [R] . Percec, V., Johansson, G. 1995

机译：从含有冠醚的液晶聚合物到锥形构件，含有自组装成管状超分子的冠醚

Cooperative recognition of C-60-ammonium substrates by a ditopic oligophenylenevinylene/crown ether host

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