Chiral 1, 2-Bis (phosphetano) benzenes: Preparation and Use in the Ru-Catalyzed Hydrogenations of Carbonyl Derivatives

Angela Marinetti; Jean-Pierre Genet; Sebastien Jus; Delphine Blanc; Virginie Ratovelomanana-Vidal

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Chiral 1, 2-Bis (phosphetano) benzenes: Preparation and Use in the Ru-Catalyzed Hydrogenations of Carbonyl Derivatives

机译：手性1,2-双（磷酸根）苯：羰基衍生物的Ru催化加氢反应的制备和应用

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Chiral 1, 2-bis (phosphetano) benzenes are readily prepared from accessible, optically pure 1,3-diol cyclic sulfates. Their ruthenium complexes catalyze the enantioselective hydrogenations of functionalized carbonyls with moderate-to-high enantiomeric excesses. High levels of diastereo- and enantioselectivity are achieved, especially in the hydrogenation of #beta#-diketones to the corresponding anti-1, 3-diols.

机译：由可及的光学纯的1，3-二醇环状硫酸盐可容易地制备手性1，2-双（磷酸根）苯。它们的钌络合物催化中度至高对映体过量的官能化羰基的对映选择性氢化。实现了高水平的非对映选择性和对映选择性，特别是在将＃beta＃-二酮氢化为相应的抗1,3-二醇时。

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《Chemistry: A European journal》 |1999年第4期|共6页
作者
Angela Marinetti; Jean-Pierre Genet; Sebastien Jus; Delphine Blanc; Virginie Ratovelomanana-Vidal;
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正文语种 eng
中图分类化学;应用化学;
关键词
catalysts; chiral phosphetanes; hydrogenations; phosphorus; ruthenium;

机译：催化剂;手性膦;氢化;磷;钌;

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1. Chiral 1, 2-Bis (phosphetano) benzenes: Preparation and Use in the Ru-Catalyzed Hydrogenations of Carbonyl Derivatives [J] . Angela Marinetti, Jean-Pierre Genet, Sebastien Jus, Chemistry: A European journal . 1999,第4期

机译：手性1,2-双（磷酸根）苯：羰基衍生物的Ru催化加氢反应的制备和应用
2. A Versatile Method for the Preparation of Enantiomeric Benzene-1,2-bis(alanine) Derivatives [J] . Bjorg S.Moller, Kjell Undheim Synthetic Communications . 2003,第24期

机译：一种制备对映体苯1,2-双（丙氨酸）衍生物的多功能方法
3. DEHYDROGENATIVE N-HETEROCYCLIZATION OF 2-(2-AMINOARYL)ETHYL ALCOHOLS TO INDOLE DERIVATIVES CATALYZED BY (μ-OXO)TETRARUTHENIUM CLUSTER/ l,2-BIS(DIPHENYLPHOSPHINO)BENZENE [J] . Teruyuki Kondo, Takashi Kanda, Daisuke Takagi Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2012,第2期

机译：2-（2-氨基芳基）乙基醇在（μ-氧代）四钌簇簇/ l，2-双（二苯基膦基）苯催化下的加氢N-杂环化为吲哚衍生物
4. Partial Hydrogenation of Benzene to Cyclohexene over Supported Ruthenium Carbonyl Cluster-Derived Catalysts [C] . Ken SUZUKI, Hiroshi ISHIDA, Hajime NAGAHARA Tokyo Conference on Advanced Catalytic Science and Technology . 2003

机译：苯对负载钌羰基簇衍生催化剂的苯对环己烯的部分氢化
5. Reversing diastereoselectivity: Chelation-controlled addition of organozincs to chiral carbonyl derivatives. [D] . Stanton, Gretchen R. 2013

机译：逆转非对映选择性：将有机锌螯合控制地添加到手性羰基衍生物中。
6. Enantioselective Iridium Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level via Transfer Hydrogenative Coupling of Allyl Acetate: Departure from Chirally Modified Allyl Metal Reagents in Carbonyl Addition [O] . In Su Kim, Ming-Yu Ngai, Michael J. Krische -1

机译：对映选择性铱通过乙酸烯丙酯的转移加氢偶联从醇或醛的氧化级催化羰基烯丙基化：脱除羰基加成中的手性改性烯丙基金属试剂
7. New chiral amino alcohol ligands derived from 1-phenylethylamine for efficient Ru-catalyzed asymmetric transfer hydrogenation [O] . Han Mei-Ling, Hu Xiang-Ping, Huang Jia-Di, 2011

机译：新的手性氨基醇配体衍生自1-苯基乙胺，用于有效的Ru催化的不对称转移氢化
8. Dialkylamino Phosphorous Metal Carbonyls. 4. Novel Phosphorus-Bridging Carbonyl Derivatives and Triphosphine Derivatives from Reactions of Tetracarbonylferrate(-II) with (Dialkylamino)dichlorophosphines 1-4 [R] . King, R. B., Wu, F. J., Holt, E. M. 1987

机译：二烷基氨基亚磷酸金属羰基化合物。 4.四羰基铁酸盐（-II）与（二烷基氨基）二氯膦1-4反应的新型磷桥联羰基衍生物和三膦衍生物

Chiral 1, 2-Bis (phosphetano) benzenes: Preparation and Use in the Ru-Catalyzed Hydrogenations of Carbonyl Derivatives

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