N.N'-Disubstituted Ureas:Influence of Substituents on the Formation of Supramolecular Polymers

Frederic Lortie; Sylvie Boileau; Laurent Bouteiller

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N.N'-Disubstituted Ureas:Influence of Substituents on the Formation of Supramolecular Polymers

机译：N.N'-双取代尿素：取代基对超分子聚合物形成的影响

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Symmetrical N,N'-disubstituted ureas have been synthesized adn characterized Among them the branched dialkylureas prepared are highly soluble in organic media Moreover dthe solutions obtined are very viscous in heptane if the branched alkyl roups are not too bulky (i.e.a methyl group on the a carbon or an ethyl group on the beta carbon) Due to the strong bifurcated hydrogen bonds between the urea moieties dhinear supromolecular polymers are formed The degree of association of these supramolecular polymers has been determined by FTIR spectroscopy.

机译：合成了对称的N，N'-二取代脲，并表征了其中制备的支链二烷基脲在有机介质中的溶解度高。另外，如果支链烷基团不太庞大，则所获得的溶液在庚烷中的粘度非常高（即a上的甲基）。碳原子或β碳原子上的乙基）由于在脲部分之间形成了强的分叉氢键，从而形成了超分子聚合物。这些超分子聚合物的缔合度已通过FTIR光谱法测定。

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《Chemistry: A European journal》 |2003年第13期|共7页
作者
Frederic Lortie; Sylvie Boileau; Laurent Bouteiller;
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正文语种 eng
中图分类化学;
关键词
IR spectroscopy; polymers; self-assembly; supra-molecular chemistry;

机译：红外光谱;聚合物;自组装;超分子化学;

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1. N.N'-Disubstituted Ureas:Influence of Substituents on the Formation of Supramolecular Polymers [J] . Frederic Lortie, Sylvie Boileau, Laurent Bouteiller Chemistry: A European journal . 2003,第13期

机译：N.N'-双取代尿素：取代基对超分子聚合物形成的影响
2. Influence of phosphonium alkyl substituents on the rheological and thermal properties of phosphonium-PAA-based supramolecular polymeric assemblies [J] . Lin X., Navailles L., Nallet F., Macromolecules . 2012,第23期

机译：alkyl烷基取代基对phospho-PAA基超分子聚合物组件的流变学和热学性能的影响
3. Self-Assembly of Diorganotin(Ⅳ) Oxides (R = Me, nBu, Ph) and 2,5-Pyridinedicarboxylic Acid to Polymeric and Trinuclear Macrocyclic Hybrids with Porous Solid-State Structures: Influence of Substituents and Solvent on the Supramolecular Structure [J] . Reyes Garcia-Zarracino, Herbert Hoepfl Journal of the American Chemical Society . 2005,第9期

机译：氧化二有机锡（Ⅳ）（R = Me，nBu，Ph）和2,5-吡啶二甲酸自组装成具有多孔固态结构的聚合物和三核大环杂化物：取代基和溶剂对超分子结构的影响
4. Supramolecular Polymerization in Liquid Crystalline Media (2):Formation of Supramolecular Copolymer [C] . Daiki Morishita, XujieZhang, Keiichi Yano 日本化学会春季年会 . 2020

机译：液晶介质中的超分子聚合（2）：中分子共聚物的形成
5. The influence of substituents and supramolecular catalysis on the rates of synthetically useful pericyclic reactions. [D] . Jones, Gavin Orlando. 2007

机译：取代基和超分子催化对合成有用的周环反应速率的影响。
6. Metallacycle-Cored Supramolecular Polymers: Fluorescence Tuning by Variation of Substituents [O] . Luonan Xu, Xi Shen, Zhixuan Zhou, -1

机译：含金属环的超分子聚合物：通过取代基的变化进行荧光调谐。
7. Conformational Plasticity of Hydrogen Bonded Bis-urea Supramolecular Polymers [O] . Patrick Brocorens, Mathieu Linares, Carine Guyard-Duhayon, 2013

机译：氢键合双脲超分子聚合物的构象可塑性
8. Synthesis of Side Chain Liquid Crystal Polymers by Living Ring Opening MetathesisPolymerization. 3. Influence of Molecular Weight, Interconnecting Unit and Substituent on the Mesomorphic behavior of Polymers with Laterally Attached Mesogens [R] . Pugh, C., Schrock, R. R. 1992

机译：活环开环复分解聚合合成侧链液晶聚合物。 3.分子量，互连单元和取代基对具有横向附着的中间体的聚合物的介晶行为的影响

N.N'-Disubstituted Ureas:Influence of Substituents on the Formation of Supramolecular Polymers

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