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首页> 外文期刊>Chemistry: A European journal >ULTRAMINE:A High-Capacity Polyethylene-Imine-Based Polymer and Its Application as a Scavenger Resin
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ULTRAMINE:A High-Capacity Polyethylene-Imine-Based Polymer and Its Application as a Scavenger Resin

机译：ULTRAMINE：一种高容量聚乙烯亚胺基聚合物及其在清除剂树脂中的应用

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摘要

The synthesis of a novel high-loading polyethylene-imine resin (ULTRAMINE) is described,and its application as a scavenger resin in various acylation reactions is demonstrated.The inverse suspension polymerization technique was used for the synthesis of well-defined spherical polymer beads.Polymer beads with different cross-linking densities were synthesized according to the degree of acryloyla-tion of the polyethylene-imine polymer.The resin was characterized by various spectroscopic techniques.The size,shape,and morphological features of the resin were demonstrated by microscopy.The resin showed excellent swelling properties in both polar and nonpolar solvents.The chemical stability of the resin in various reagents and solvents was investigated and moni-tored by IR spectroscopy.The mechanical stability of the beads was determined by a single-bead compressive experiment.The ULTRAMINE beads can be used as an excellent scavenger for excess acylating reagent,as demonstrated for a variety of reactions.UL-TRAMINE-red resin was derived from ULTRAMINE through exhaustive reduction of the amide carbonyl groups to yield an all-amine resin.
机译：描述了一种新型的高载量聚乙烯亚胺树脂（ULTRAMINE）的合成，并证明了其作为清除剂树脂在各种酰化反应中的应用。逆悬浮聚合技术被用于合成明确的球形聚合物珠粒。根据聚乙烯亚胺聚合物的丙烯酰基化程度，合成了具有不同交联密度的聚合物珠。通过多种光谱技术对树脂进行了表征，并通过显微镜观察了其尺寸，形状和形态特征。该树脂在极性和非极性溶剂中均表现出优异的溶胀性能。通过红外光谱研究和监测树脂在各种试剂和溶剂中的化学稳定性，并通过单珠压缩实验确定珠的机械稳定性。 ULTRAMINE珠可以用作过量酰化试剂的优异清除剂，如多种UL-TRAMINE-红色树脂是从ULTRAMINE衍生出来的，方法是彻底还原酰胺羰基，得到全胺树脂。

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