Toward the synthesis of the antibiotic branimycin: Novel approaches to highly substituted cis-decalin systems

Mulzer J; Castagnolo D; Felzmann W; Marchart S; Pilger C; Enev VS

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Toward the synthesis of the antibiotic branimycin: Novel approaches to highly substituted cis-decalin systems

机译：合成抗生素布雷尼霉素：高度取代的顺式十氢化萘系统的新方法

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A variety of highly functionalized cis-decalin systems have been prepared by means of the stereoselective transannular Diels-Alder (TADA) reaction of a (Z,E,Z,Z)-tetraene macrolide, and by means of intramolecular nitrile oxide olefin (INOC) or ring-closing metathesis (RCM) annulations to quinic acid derivatives.

机译：通过（Z，E，Z，Z）-四烯大环内酯的立体选择性跨环Diels-Alder（TADA）反应，以及通过分子内一氧化氮烯烃（INOC）制备了各种高度官能化的顺式十氢化萘系统）或闭环复分解（RCM）环成奎宁酸衍生物。

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《Chemistry: A European journal》 |2006年第23期|共10页
作者
Mulzer J; Castagnolo D; Felzmann W; Marchart S; Pilger C; Enev VS;
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正文语种 eng
中图分类化学;
关键词
annulation; Diels-Alder reaction; ring-closing metathesis; stereoselective synthesis; synthesis design; OLEFIN-METATHESIS CATALYSTS; STEREOSELECTIVE-SYNTHESIS; STEREOSPECIFICALLY ANTI; S(E)2' REACTIONS; (-)-QUINIC ACID; CORE; NARGENICINS; ALDEHYDES; EFFICIENT; ADDITIONS;

机译：环化;Diels-Alder反应;闭环易位;立体选择性合成;合成设计;烯烃复分解催化剂;立体选择性合成;立体特定的抗;S（E）2'反应;（-）-奎尼酸;核;核苷;ALDEHYDES;高效;添加;

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1. Toward the synthesis of the antibiotic branimycin: Novel approaches to highly substituted cis-decalin systems [J] . Mulzer J, Castagnolo D, Felzmann W, Chemistry: A European journal . 2006,第23期

机译：合成抗生素布雷尼霉素：高度取代的顺式十氢化萘系统的新方法
2. Toward the total synthesis of luminamicin; an anaerobic antibiotic: construction of highly functionalized cis-decalin containing a bridged ether moiety [J] . Ando Hiroyasu, Kimishima Aoi, Ohara Motoyoshi, The Journal of Antibiotics: An International Journal . 2018,第2期

机译：朝向Luminamicin的总合成; 一种厌氧抗生素：含有桥面醚部分的高官能化CIS-DECALIN的构建
3. Approaches to the Synthesis of Highly Substituted Aromatic and Fused Rings: Metal-Catalysed versus Thermal Cyclisation [J] . Philip J. Parsons, Lewis A. T. Allen, Daniel R. Jones, Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2018,第1期

机译：高度取代的芳香和融合环的合成方法：金属催化与热环化
4. Highly efficient, one-pot, solvent-free synthesis of highly substituted imidazoles using molecular iodine as catalyst [C] . Yi-Ming Ren, Chun Cai International Conference on Chemical, Material and Metallurgical Engineering . 2012

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5. Generalization of highly γ-regioselective substitutions in allyl halides by alkylzincs and applications to zinc-ene cyclizations and the synthesis of (R)-(+)-dihydro-α-ionone [D] . Ivanov, Roman A. 2008

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6. Synthesis of highly substituted benzene ring systems through three-component coupling of enyne imines Fischer carbene complexes and electron-deficient alkynes [O] . Bishnu Dhakal, Lalith S. R. Gamage, Yanshi Zhang, -1

机译：通过烯炔亚胺菲舍尔卡宾配合物和缺电子炔烃的三组分偶联合成高度取代的苯环系统
7. cis-Decalins from Quinic Acid: Toward a Synthesis of Branimycin [O] . -1

机译：来自醋酸的顺式癸苯胺：朝向Branimycin的合成

Toward the synthesis of the antibiotic branimycin: Novel approaches to highly substituted cis-decalin systems

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