Anhydrous Phosphazenium Fluorides as Sources for Extremely Reactive Fluoride Ions in Solution

Reinhard Schwesinger; Reinhard Link; Peter Wenzl; Sebastian Kossek

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Anhydrous Phosphazenium Fluorides as Sources for Extremely Reactive Fluoride Ions in Solution

机译：无水氟化磷用作溶液中极活泼的氟离子的来源

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Several peralkylated polyaminophosphazenium cations were evaluated for the generation of novel anhydrous F~- salts.Two of them have been characterized by X-ray analysis and are particularly soluble,even in apolar aprotic solvents like benzene or THF,one of them even at - 30 deg C.Such solutions probably represent the most basic metal-free and stable media known to date.Comparison of these fluorides with known F~- sources demonstrates that they are of unprecedented reactivity and selectivity in E2 elimination reactions.

机译：对几种全烷基化的聚氨基磷腈鎓阳离子进行了评估，以生成新型的无水F〜-盐。其中的两种已通过X射线分析表征，并且特别可溶，甚至可溶于非极性非质子溶剂，如苯或THF，其中一种甚至在-30这种溶液可能代表了迄今为止已知的最基本的无金属和稳定的介质。这些氟化物与已知的F-来源的比较表明，它们在E2消除反应中具有空前的反应性和选择性。

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《Chemistry: A European journal》 |2006年第2期|共8页
作者
Reinhard Schwesinger; Reinhard Link; Peter Wenzl; Sebastian Kossek;
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正文语种 eng
中图分类化学;
关键词
cations; elimination; fluorine; phosphazenes phosphorus;

机译：阳离子;消除;氟;磷腈;

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1. Anhydrous Phosphazenium Fluorides as Sources for Extremely Reactive Fluoride Ions in Solution [J] . Reinhard Schwesinger, Reinhard Link, Peter Wenzl, Chemistry: A European journal . 2006,第2期

机译：无水氟化磷用作溶液中极活泼的氟离子的来源
2. Lewis Acidic Behavior of MoOF4 towards the Alkali Metal Fluorides in Anhydrous Hydrogen Fluoride Solutions [J] . Stene Riane E., Scheibe Benjamin, Karttunen Antti J., European journal of inorganic chemistry . 2019,第32期

机译：MoOF4的路易斯酸性行为朝向无水氟化氢溶液中的碱金属氟化物
3. Synthesis, Characterization, and Reactivity of Thermally Stable Anhydrous Quaternary Ammonium Fluorides [J] . Elias Shlomi, Karton-Lifshin Naama, Yehezkel Lea, Organic letters . 2017,第12期

机译：热稳定无水季铵氟化物的合成，表征和反应性
4. Analysis of Beryllium Fluoride (BeF_2) and Strontium Fluoride (SrF_2) Thin Films Deposited by Improved Solution Growth Technique for Industrial Applications [C] . P. A. Ilenikhena International Conference on Engineering Research and Development . 2007

机译：采用改进的溶液生长技术沉积的氟化铍（BEF_2）和氟化锶（SRF_2）薄膜进行工业应用
5. Available fluoride ion in solution and one minute fluoride release rate of a toothpaste formulation. [D] . Mueller, Elizabeth. 2014

机译：溶液中的可用氟离子和牙膏配方的一分钟氟释放速率。
6. Calcium Fluoride Precipitation and Deposition From 12 mmol/L Fluoride Solutions With Different Calcium Addition Rates [O] . M Markovic, S Takagi, LC Chow, 2009

机译：不同钙添加量的12 mmol / L氟化物溶液中氟化钙的沉淀和沉积
7. Preparation of Tri-O-benzoyl-2-deoxy-alpha-D-ribo-hexopyranosyl Fluoride from Derivatives of D-Glucal and Anhydrous Hydrogen Fluoride. [O] . Inge Lundt, Christian Pedersen, Bente Olsen, 1970

机译：用D-葡萄糖和无水氟化氢衍生物制备三-O-苯甲酰-2-脱氧-α-D-核己烯基氟化物。

Anhydrous Phosphazenium Fluorides as Sources for Extremely Reactive Fluoride Ions in Solution

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