Enhanced Fluorescence of Remote Functionalized Diaminodicyanoquinodimethanes in the Solid State and Fluorescence Switching in a Doped Polymer by Solvent Vapors

S.Jayanty; T.P.Radhakrishnan

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Enhanced Fluorescence of Remote Functionalized Diaminodicyanoquinodimethanes in the Solid State and Fluorescence Switching in a Doped Polymer by Solvent Vapors

机译：远程官能化的二氨基二氰基喹二甲烷在固态中的增强荧光和掺杂聚合物中的溶剂蒸气的荧光转换

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摘要

Remote functionalized zwit-terionic diaminodicyanoquinodime-thanes are found to exhibit a dramatic enhancement of light emission in the solid state and when doped in polymer films,as compared to the solution state.Crystal structure analysis of prototypical molecules reveals the role of the remote functionality in the solid state molecular organization.Semiem-pirical quantum chemical computations provide a viable model to explain the interesting phenomenon of fluores cence enhancement as arising from the inhibition of geometry relaxation of the vertical excited state to a nonemit-ting state.The reversible switching of a doped polymer film fluorescence triggered by solvent vapors is demonstrated.

机译：与溶液状态相比，发现远程功能化的zwit-叔离子二氨基二氰基喹啉二甲酸酯在固态和掺杂在聚合物薄膜中时能显着增强发光。原型分子的晶体结构分析揭示了远程功能在半柱式量子化学计算提供了一个可行的模型来解释有趣的荧光现象增强现象，该现象是由于垂直激发态向非发光态的几何弛豫受到抑制而引起的。证明了由溶剂蒸气触发的掺杂聚合物薄膜的荧光。

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《Chemistry: A European journal》 |2004年第3期|共1页
作者
S.Jayanty; T.P.Radhakrishnan;
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正文语种 eng
中图分类化学;
关键词
diaminodicyanoquinodimethane; fluorescence enhancement; semiempirical calculations; solvent switch;

机译：二氨基二氰基喹二甲烷荧光增强半经验计算溶剂转换;

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1. Enhanced Fluorescence of Remote Functionalized Diaminodicyanoquinodimethanes in the Solid State and Fluorescence Switching in a Doped Polymer by Solvent Vapors [J] . S.Jayanty, T.P.Radhakrishnan Chemistry: A European journal . 2004,第3期

机译：远程官能化的二氨基二氰基喹二甲烷在固态中的增强荧光和掺杂聚合物中的溶剂蒸气的荧光转换
2. A Switchable fluorescence solid sensor for Hg~(2+) detection in aqueous media based on a photocrosslinked membrane functionalized with (benzimidazolyl)methyl-piperazine derivative of 1,8-naphthalimide [J] . Fernandez-Alonso S., Corrales T., Pablos J. L., Sensors and Actuators . 2018,第OCTa期

机译：基于以1,8-萘二甲酰亚胺的（苯并咪唑基）甲基-哌嗪衍生物官能化的光交联膜，用于水介质中Hg〜（2+）检测的可切换荧光固体传感器
3. Benzothiazole, pyridine functionalized triphenylamine based fluorophore for solid state fluorescence switching, Fe~(3+) and picric acid sensing [J] . Arockiam Jesin Beneto, Ayyanar Siva Sensors and Actuators . 2017,第apra期

机译：苯并噻唑，吡啶官能化的三苯胺基荧光团，用于固态荧光切换，Fe〜（3+）和苦味酸传感
4. ICG-loaded polymeric nanocapsules functionalized with anti-HER2 for targeted fluorescence imaging and photodestruction of ovarian cancer cells [C] . Baharak Bahmani, Yadir Guerrero, Valentine Vullev, Reporters, markers, dyes, nanoparticles, and molecular probes for biomedical applications V . 2013

机译：ICG载有抗HER2功能的聚合物纳米胶囊，用于靶向荧光成像和卵巢癌细胞的光破坏
5. MOLECULAR ORIENTATION AND RELAXATION PHENOMENA IN POLYMER SOLIDS STUDIED BY ANALYSIS OF FLUORESCENCE POLARIZATION [D] . Nishio, Yoshiyuki 1982

机译：荧光极化分析法制备的聚合物分子取向与弛豫现象。
6. Fluorescence Switchable Conjugated Polymer Microdisk Arrays by Cosolvent Vapor Annealing [O] . Hiroshi Yamagishi, Tokiya Matsui, Yusuke Kitayama, 2021

机译：荧光可切换共轭聚合物微型磁盘阵列通过共溶剂蒸汽退火
7. Fluorescence Switchable Conjugated Polymer Microdisk Arrays by Cosolvent Vapor Annealing [O] . Hiroshi Yamagishi, Tokiya Matsui, Yusuke Kitayama, 2021

机译：荧光可切换共轭聚合物微型磁盘阵列通过共溶剂蒸汽退火
8. Diverse, Highly Sensitive, Fluorescence Sensor Libraries: Instrumentation for the Investigation of Functionalized Conjugated Polymer Assemblies [R] . Swager, T. M. 1999

机译：多样，高灵敏度的荧光传感器库：用于研究功能化共轭聚合物组件的仪器

Enhanced Fluorescence of Remote Functionalized Diaminodicyanoquinodimethanes in the Solid State and Fluorescence Switching in a Doped Polymer by Solvent Vapors

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