High oxidation state organometallic chemistry in aqueous media: New opportunities for catalysis and electrocatalysis

Poli R.

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High oxidation state organometallic chemistry in aqueous media: New opportunities for catalysis and electrocatalysis

机译：水性介质中的高氧化态有机金属化学：催化和电催化的新机会

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Molybdenum has been used as a case study for the rational development of a new domain of organometallic chemistry, combining oxo-stabilized high oxidation state metals and aqueous media. The pH-dependent conversion of oxo, hydroxo, and aqua ligands allows the opening of free coordination sites, while the use of a redox active metal opens possible pathways for coupled proton and electron transfer to and from activated substrates. While our work has so far only concentrated on synthesis and analytical investigations, the development of catalytic and electrocatalytic processes in water or aqueous media is a promising application of this new research area. [References: 39]

机译：钼已被用作案例研究，以合理开发有机氧化学的新领域，结合了氧稳定的高氧化态金属和水性介质。氧，氧和水配体的pH依赖型转化允许打开自由配位点，而氧化还原活性金属的使用则打开了质子和电子耦合进出活化基质的可能途径。虽然到目前为止我们的工作仅集中在合成和分析研究上，但是在水或水性介质中催化和电催化方法的发展是这一新研究领域的有希望的应用。 [参考：39]

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《Chemistry: A European journal》 |2004年第2期|共10页
作者
Poli R.;
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正文语种 eng
中图分类化学;
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Mass spectrometry; Molybdenum; O ligands; Water chemistry; X-ray structures; Oxo complexes; Mass-spectrometry; Water; (c5me5)(2)mo2o5; Derivatives; Molybdenum; Reduction; Oxides; Reactivity;

机译：质谱;钼;O配体;水化学;X射线结构;氧配合物;质谱;水;（c5me5）（2）mo2o5;衍生物;钼;还原;氧化物;反应性;

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1. High oxidation state organometallic chemistry in aqueous media: New opportunities for catalysis and electrocatalysis [J] . Poli R. Chemistry: A European journal . 2004,第2期

机译：水性介质中的高氧化态有机金属化学：催化和电催化的新机会
2. Selective electrocatalysis of alkene oxidations in aqueous media. Electrochemical and spectral characterization of oxo-ferryl porphyrin, oxo-ferryl porphyrin radical cation and their reaction products with alkenes at room temperature [J] . Mao-huang Liu, Y. Oliver Su Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry . 1998,第1期

机译：水性介质中烯烃氧化的选择性电催化。氧-轮渡卟啉，氧-轮卟啉自由基阳离子及其与烯烃的反应产物在室温下的电化学和光谱表征
3. Organometallic catalysts in synthetic organic chemistry: From reactions in aqueous media to gold catalysis [J] . Jean-Pierre Genet, Sylvain Darses, Veronique Michelet Pure and Applied Chemistry . 2008,第5期

机译：合成有机化学中的有机金属催化剂：从水性介质中的反应到金催化
4. Electrocatalysis of Oxygen Reduction Reaction and Ethanol Oxidation Reaction on 'Multi-Functional' Catalysts in Alkaline Media [C] . R. Chen, J. Guo Electrochemical Conference on Energy amp; the Environment . 2014

机译：碱性介质中“多功能”催化剂上氧还原反应和乙醇氧化反应的电催化
5. Organometallic chemistry in unusual media: Water and supercritical carbon dioxide as solvents for organometallic chemistry. [D] . Stafford, Jessica Nicole White. 1994

机译：特殊介质中的有机金属化学：水和超临界二氧化碳作为有机金属化学的溶剂。
6. Enhanced Oxygen Electrocatalysis in HeterostructuredCeria Electrolytes for Intermediate-Temperature Solid Oxide Fuel Cells [O] . Tao Hong, *, Yanxiang Zhang, 2018

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7. Redox Conversion of Chromium(VI) and Arsenic(III) with the Intermediates of Chromium(V) and Arsenic(IV) via AuPd/CNTs Electrocatalysis in Acid Aqueous Solution [O] . Sun Meng, Zhang Gong, Qin Yinghua, 2015

机译：通过AuPd / CNTs在酸性水溶液中电催化铬（VI）和砷（IV）中间物氧化铬（VI）和砷（III）的氧化还原转化

High oxidation state organometallic chemistry in aqueous media: New opportunities for catalysis and electrocatalysis

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