High Oxidation State Organometallic Chemistry in Aqueous Media:New Opportunities for Catalysis and Electrocatalysis

Rinaldo Poli

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High Oxidation State Organometallic Chemistry in Aqueous Media:New Opportunities for Catalysis and Electrocatalysis

机译：水性介质中的高氧化态有机金属化学：催化和电催化的新机遇

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Molybdenum has been used as a case study for the rational development of a new domain of organometallic chemistry,combining oxo-stabilized high oxidation state metal and aqueous media.The pH-dependent conversion of oxo,hydroxo,and aqua ligands allows the opening of free coordination sites,while the use of a redox active metal opens possible pathways for coupled proton and electron transfer to and from activated substrates.While our work has so far only concentrated on synthesis and analytical investigations,the development of catalytic and electrocatalytic processes in water or aqueous media is a promising application of this new research area.

机译：钼已被用作案例研究，以合理开发有机金属化学的新领域，结合了氧稳定的高氧化态金属和水性介质。氧，氢氧和水配体的pH依赖性转化可释放自由的配合位点，而氧化还原活性金属的使用则为质子和电子耦合进出活化基质开辟了可能的途径。尽管到目前为止，我们的工作仅集中在合成和分析研究，在水中或水中催化和电催化过程的发展。水性介质是该新研究领域的有前途的应用。

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《Chemistry: A European journal》 |2004年第2期|共9页
作者
Rinaldo Poli;
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正文语种 eng
中图分类化学;
关键词
mass spectrometry; molybdenum; O ligands; water chemistry;

机译：质谱钼O配体水化学;

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1. High oxidation state organometallic chemistry in aqueous media: New opportunities for catalysis and electrocatalysis [J] . Poli R. Chemistry: A European journal . 2004,第2期

机译：水性介质中的高氧化态有机金属化学：催化和电催化的新机会
2. Selective electrocatalysis of alkene oxidations in aqueous media. Electrochemical and spectral characterization of oxo-ferryl porphyrin, oxo-ferryl porphyrin radical cation and their reaction products with alkenes at room temperature [J] . Mao-huang Liu, Y. Oliver Su Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry . 1998,第1期

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High Oxidation State Organometallic Chemistry in Aqueous Media:New Opportunities for Catalysis and Electrocatalysis

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