DETERMINATION OF THE REGIOCHEMISTRY OF INSECT EPOXIDE HYDROLASE CATALYZED EPOXIDE HYDRATION OF JUVENILE HORMONE BY O-18-LABELING STUDIES

Linderman RJ.; Haney C.; Roe RM.; Walker EA.

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DETERMINATION OF THE REGIOCHEMISTRY OF INSECT EPOXIDE HYDROLASE CATALYZED EPOXIDE HYDRATION OF JUVENILE HORMONE BY O-18-LABELING STUDIES

机译：O-18标记法测定昆虫环氧合酶催化少年激素环氧加氢的区域化学。

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The regiochemistry of Trichoplusia ni epoxide hydrolase catalyzed epoxide hydration of insect juvenile hormone (JH) III has been determined by GC/MS studies of O-18-label incorporation. Nucleophilic addition occurs at C10 of the C10,11 epoxide of JH III. The identification of isotopically labeled and unlabeled diol from the enzyme catalyzed hydration reaction in (H2O)-O-18 implies that a covalently bound ester intermediate may be involved in the mechanism of the reaction. [References: 38]

机译：通过O /-18标记掺入的GC / MS研究，已确定了Trichoplusia ni环氧水解酶催化的昆虫幼激素（JH）III的环氧水合的区域化学。亲核加成发生在JH III的C10,11环氧化物的C10处。从（H2O）-O-18中的酶催化水合反应中鉴定出同位素标记的和未标记的二醇意味着，共价键合的酯中间体可能参与该反应的机理。 [参考：38]

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《Tetrahedron》 |1995年第40期|共12页
作者
Linderman RJ.; Haney C.; Roe RM.; Walker EA.;
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正文语种 eng
中图分类有机化学;
关键词
Manduca-sexta; Enzymatic hydration; Tobacco hornworm; Mechanism; Esterase; Regioselectivity; Identification; Expression; Hydrolysis; Hydrase;

机译：曼陀罗;酶促水合作用;烟草天牛;机理;酯酶;区域选择性;鉴定;表达;水解;水合;

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1. DETERMINATION OF THE REGIOCHEMISTRY OF INSECT EPOXIDE HYDROLASE CATALYZED EPOXIDE HYDRATION OF JUVENILE HORMONE BY O-18-LABELING STUDIES [J] . Linderman RJ., Haney C., Roe RM., Tetrahedron . 1995,第40期

机译：O-18标记法测定昆虫环氧合酶催化少年激素环氧加氢的区域化学。
2. Publisher Correction: Juvenile Hormone Epoxide Hydrolase: a Promising Target for Hemipteran Pest Management [J] . Abudourusuli Tusun, Ming Li, Xiangzhi Liang, Scientific reports. . 2018,第1期

机译：出版商校正：青少年激素环氧化物水解酶：半翅目害虫管理的有希望的目标
3. Silencing of juvenile hormone epoxide hydrolase gene (ce:italic>Nljheh/ce:italic>) enhances short wing formation in a macropterous strain of the brown planthopper, ce:italic>Nilaparvata lugens/ce:italic> [J] . Jing Zhao, Yunlong Zhou, Xiang Li, Journal of Insect Physiology . 2017,第期

机译：少年激素环氧化物水解酶基因（斜体：斜体> NlJheh＆ / Ce：斜体>）增强了棕色Planthopper的宏观株的短翼形成，＆ Ce：斜体> NileaParvata Lugens＆ / ce：斜体>
4. RNA interference (RNAi) technology of microRNAs targeting juvenile hormone epoxide hydrolase (JHEH) gene for increased silk productivity in Bombyx mori [C] . D. M. Mamatha, S. Jyothi, V. V. Satyavathi, International Conference on Computing for Sustainable Global Development . 2016

机译：靶向少年激素环氧化物水解酶（JHEH）基因的MicroRNA干扰（RNAi）技术在Bombyx Mori中提高丝绸生产率
5. Synthesis and analysis of mechanism based inhibitors of juvenile hormone epoxide hydrolase from insect Trichoplusia ni. [D] . Fetterolf, Brandon John. 2002

机译：昆虫天花粉虱幼体激素环氧水解酶抑制剂的合成及机理分析。
6. Characterization and Expression Profiles of Juvenile Hormone Epoxide Hydrolase From Lymantria dispar (Lepidoptera: Lymantridae) and RNA Interference by Ingestion [O] . Rongrong Wen, Buyong Wang, Bowen Wang, 2018

机译：狼尾草幼虫激素环氧水解酶的表征和表达特征及食入RNA干扰
7. A Photorhabdus natural product inhibits insect juvenile hormone epoxide hydrolase [O] . Nollmann, FI., Heinrich, AK., Brachmann, AO., 2015

机译：photorhabdus天然产物抑制昆虫幼年激素环氧化物水解酶

DETERMINATION OF THE REGIOCHEMISTRY OF INSECT EPOXIDE HYDROLASE CATALYZED EPOXIDE HYDRATION OF JUVENILE HORMONE BY O-18-LABELING STUDIES

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