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首页> 外文期刊>The American mineralogist >Phase boundary between perovskite and post-perovskite structures in MnGeO_3 determined by in situ X-ray diffraction measurements using sintered diamond anvils
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Phase boundary between perovskite and post-perovskite structures in MnGeO_3 determined by in situ X-ray diffraction measurements using sintered diamond anvils

机译:MnGeO_3中钙钛矿和钙钛矿后结构之间的相界通过使用烧结金刚石砧的原位X射线衍射测量确定

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摘要

To determine the phase boundary between the perovskite and post-perovskite structures in MnGeO3, in situ X-ray observations were carried out at pressures of 57-68 GPa and temperatures of 1000-1900 K using the Kawai-type high-pressure apparatus equipped with sintered diamond anvils interfaced with synchrotron radiation. The phase boundary was determined to be P (GPa) = 39.2 + 0.013T (K) based on Tsuchiya's (2003) gold pressure scale. The Clapeyron slope, dP/dT, of 13(+12/-5) MPa/K, determined in the present study is larger that of MgGeO3 and MgSiO3.
机译:为了确定MnGeO3中钙钛矿和钙钛矿后结构之间的相界,使用配备了Kawai型高压装置的Kawai型高压装置在57-68 GPa的压力和1000-1900 K的温度下进行了原位X射线观察。烧结金刚石砧与同步加速器辐射接触。根据土屋(2003)的金压力标度,确定相界为P(GPa)= 39.2 + 0.013T(K)。在本研究中确定的Clapeyron斜率dP / dT为13(+ 12 / -5)MPa / K,比MgGeO3和MgSiO3大。

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